A synchronous defluorination-oxidation process for degradation of fluoroarenes with PEC
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FLUOROARENE (FA) DERIVATIVES ARE PERSISTENT POLLUTANTS IN WASTEWATER THAN CAN CAUSE ECOLOGICAL RISK. THE CLEAVAGE OF C-F BONDS AND MINERALIZATION OF INTERMEDIATES ARE TWO CHALLENGES FOR ELIMINATION OF FAS. HERE WE DEVELOPED A SYNCHRONOUS DEFLUORINATION-OXIDATION PROCESS WITH A PEC DEVICE, WHICH COUPLES THE PHOTOLYSIS DEFLUORINATION WITH •OH-INITIATED OXIDATION. EFFICIENT DEFLUORINATION AND TOC REMOVAL (BOTH OVER 99.9%) WERE SUCCESSFULLY ACHIEVED UNDER MILD CONDITIONS.
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Fluoroarene (FA) derivatives are receiving more and more attention due to their widespread applications in the synthesis of pharmaceuticals, agrochemicals and organic compounds with special functions. However, as a consequence of their wide applications, the discharged FAs in industrial wastewater cause most serious environmental pollution. The toxicity, persistence, and bioaccumulation of FAs pose considerable risks to ecosystems and human health. For instance, as a typical FAs, 4-fluorophenol (4-FP) is recognized as a carcinogen in the registry of toxic effects of chemical substances.
There are two fundamental challenges needing to be addressed in regard to the degradation of FAs. First, the cleavage of C‒F bonds, which is critical to avoid the formation of toxic or persistent fluorinated byproducts. Second, the complete oxidation of defluorinated intermediates, such as aromatic or aliphatic derivatives, which is essential to enable the remediation of aquatic environment. An efficient process for elimination of FAs must be with both high defluorination efficiency and high oxidation activity. Although many efforts have been made to develop degradation methods for FAs, the cleavage of C‒F bonds using electron-deficient oxidants under oxidative conditions is inefficient because of the high electronegativity of fluorine. Besides, the application of reduction defluorination process is limited due to high cost and strict reaction conditions, such as the requirement of noble metal-based catalysts or inert atmosphere. Therefore, it is urgent to develop efficient and eco-friendly technologies for the complete degradation of FAs in wastewater under mild conditions.
Recently, a research team led by Prof. Can Li from Dalian Institute of Chemical Physics, Chinese Academy Sciences, reported a synchronous defluorination-oxidation process for efficient degradation of FAs with photoelectrocatalysis (PEC). The approach was coupled the photolysis defluorination with •OH-initiated oxidation processes. Thus, efficient defluorination and TOC removal (both over 99.9%) were successfully achieved under mild conditions. A scale-up pilot system was designed to demonstrate the deep treatment of FAs for practical application. The results were published in Chinese Journal of Catalysis (https://doi.org/10.1016/S1872-2067(23)64559-0).
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About the Journal
Chinese Journal of Catalysis is co-sponsored by Dalian Institute of Chemical Physics, Chinese Academy of Sciences and Chinese Chemical Society, and it is currently published by Elsevier group. This monthly journal publishes in English timely contributions of original and rigorously reviewed manuscripts covering all areas of catalysis. The journal publishes Reviews, Accounts, Communications, Articles, Highlights, Perspectives, and Viewpoints of highly scientific values that help understanding and defining of new concepts in both fundamental issues and practical applications of catalysis. Chinese Journal of Catalysis ranks among the top one journals in Applied Chemistry with a current SCI impact factor of 16.5. The Editors-in-Chief are Profs. Can Li and Tao Zhang.
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JOURNAL
Chinese Journal of Catalysis
ARTICLE TITLE
A synchronous defluorination-oxidation process for efficient mineralization of fluoroarenes with photoelectrocatalysis
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