Monday, November 18, 2024

 

NASA satellites reveal abrupt drop in global freshwater levels



The Earth’s total amount of freshwater dropped abruptly starting in May 2014 and has remained low ever since. The shift could indicate Earth's continents have entered a persistently drier phase.



NASA/Goddard Space Flight Center

Global Freshwater Decline 

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This map shows the years that terrestrial water storage hit a 22-year minimum (i.e., the land was driest) at each location, based on data from the GRACE and GRACE/FO satellites. A significantly large portion of the global land surface reached this minimum in the nine years since 2015, which happen to be the nine warmest years in the modern temperature record.

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Credit: Image by NASA Earth Observatory/Wanmei Liang with data courtesy of Mary Michael O’Neill




An international team of scientists using observations from NASA-German satellites found evidence that Earth’s total amount of freshwater dropped abruptly starting in May 2014 and has remained low ever since. Reporting in Surveys in Geophysics, the researchers suggested the shift could indicate Earth's continents have entered a persistently drier phase.

From 2015 through 2023, satellite measurements showed that the average amount of freshwater stored on land — that includes liquid surface water like lakes and rivers, plus water in aquifers underground — was 290 cubic miles (1,200 cubic km) lower than the average levels from 2002 through 2014, said Matthew Rodell, one of the study authors and a hydrologist at NASA’s Goddard Space Flight Center in Greenbelt, Maryland. “That’s two and a half times the volume of Lake Erie lost.”

During times of drought, along with the modern expansion of irrigated agriculture, farms and cities must rely more heavily on groundwater, which can lead to a cycle of declining underground water supplies: freshwater supplies become depleted, rain and snow fail to replenish them, and more groundwater is pumped. The reduction in available water puts a strain on farmers and communities, potentially leading to famine, conflicts, poverty, and an increased risk of disease when people turn to contaminated water sources, according to a UN report on water stress published in 2024.

The team of researchers identified this abrupt, global decrease in freshwater using observations from the Gravity Recovery and Climate Experiment (GRACE) satellites, operated by the German Aerospace Center, German Research Centre for Geosciences, and NASA. GRACE satellites measure fluctuations in Earth’s gravity on monthly scales that reveal changes in the mass of water on and under the ground. The original GRACE satellites flew from March 2002 to October 2017. The successor GRACE–Follow On (GRACE–FO) satellites  launched in May 2018.

The decline in global freshwater reported in the study began with a massive drought in northern and central Brazil, and was followed shortly by a series of major droughts in Australasia, South America, North America, Europe, and Africa. Warmer ocean temperatures in the tropical Pacific from late 2014 into 2016, culminating in one of the most significant El Niño events since 1950, led to shifts in atmospheric jet streams that altered weather and rainfall patterns around the world. However, even after El Niño subsided, global freshwater failed to rebound.  In fact, Rodell and team report that 13 of the world’s 30 most intense droughts observed by GRACE occurred since January 2015. Rodell and colleagues suspect that global warming might be contributing to the enduring freshwater depletion.

Global warming leads the atmosphere to hold more water vapor, which results in more extreme precipitation, said NASA Goddard meteorologist Michael Bosilovich. While total annual rain and snowfall levels may not change dramatically, long periods between intense precipitation events allow the soil to dry and become more compact. That decreases the amount of water the ground can absorb when it does rain. 

“The problem when you have extreme precipitation,” Bosilovich said, “is the water ends up running off,” instead of soaking in and replenishing groundwater stores. Globally, freshwater levels have stayed consistently low since the 2014-2016 El Niño, while more water remains trapped in the atmosphere as water vapor. “Warming temperatures increase both the evaporation of water from the surface to the atmosphere, and the water-holding capacity of the atmosphere, increasing the frequency and intensity of drought conditions,” he noted.

While there are reasons to suspect that the abrupt drop in freshwater is largely due to global warming, it can be difficult to definitively link the two, said Susanna Werth, a hydrologist and remote sensing scientist at Virginia Tech, who was not affiliated with the study. “There are uncertainties in climate predictions,” Werth said. “Measurements and models always come with errors.”

It remains to be seen whether global freshwater will rebound to pre-2015 values, hold steady, or resume its decline. Considering that the nine warmest years in the modern temperature record coincided with the abrupt freshwater decline, Rodell said, “We don’t think this is a coincidence, and it could be a harbinger of what’s to come.”

 

Novel magnetic field integration enhances green hydrogen peroxide production




Advanced Institute for Materials Research (AIMR), Tohoku University
Title Picture 

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Credit: ©Hao Li et al.




Researchers have achieved a breakthrough in improving the efficiency of an electrochemical reaction that produces hydrogen peroxide - a vital chemical for industrial applications such as disinfection, bleaching, and sewage treatment. This reaction, called the oxygen reduction reaction (ORR), was improved by developing a new class of heterogeneous molecular catalysts with an integrated magnetic field.

The conventional methods of producing hydrogen peroxide (H2O2) have unfortunate downsides. The process is energy-intensive, and the concentrated end product is difficult to transport safely. To face this issue, the research team looked towards an electrochemical method that is not only more efficient, but also environmentally friendly.

The research team designed a novel catalyst by anchoring cobalt phthalocyanine (CoPc) molecules on carbon black (CB), then integrating it with polymer-protected magnetic (Mag) nanoparticles. This unique structure enables effective spin state manipulation of the cobalt active sites, significantly enhancing catalytic performance.

The researchers discovered the CoPc/CB-Mag catalyst achieved a remarkable H2O2 production efficiency of 90% and significantly enhanced the reaction's efficiency. Notably, the catalyst requires only minimal amounts of magnetic materials - up to seven orders of magnitude less than previous approaches - making it both safer and more practical for large-scale applications.

"Our integrated magnetic field approach can shift the cobalt center from low-spin to high-spin state without modifying its atomic structure," said Di Zhang of the Advanced Institute for Materials Research (WPI-AIMR), "This spin transition dramatically improves the catalyst's intrinsic activities in both oxygen reduction and evolution reactions."

To understand the fundamental mechanism behind this new catalyst, they used a technique called comprehensive density functional theory (DFT) calculations. Understanding why and how it works is important for future studies. "We found that the high-spin Co site exhibits stronger binding with oxygen-containing intermediates, which is crucial for efficient catalysis," explained Associate Professor Hao Li, "The magnetic field-induced spin polarization also facilitates electron transfer and spin transitions during the reaction steps, boosting the catalytic kinetics."

"The combination of experimental results and theoretical insights provides a comprehensive picture of how magnetic fields can enhance catalytic performance," added Li, "This can serve as guidance when designing new catalysts in the future."

The findings could lead to the rational design of catalytic active materials, targeting for more efficient and environmentally friendly pathways to produce hydrogen peroxide and other value-added chemicals, contributing to global efforts in sustainable industrial processes and carbon-neutral energy technologies.

Integration of magnetic nanoparticles with molecular catalysts: Schematic illustration showing the CoPc/CB-Mag catalyst with polymer-protected magnetic nanoparticles, enabling spin state manipulation of cobalt centers. 

CREdit

©Hao Li et al.

About the World Premier International Research Center Initiative (WPI)

The WPI program was launched in 2007 by Japan's Ministry of Education, Culture, Sports, Science and Technology (MEXT) to foster globally visible research centers boasting the highest standards and outstanding research environments. Numbering more than a dozen and operating at institutions throughout the country, these centers are given a high degree of autonomy, allowing them to engage in innovative modes of management and research. The program is administered by the Japan Society for the Promotion of Science (JSPS).

See the latest research news from the centers at the WPI News Portal: https://www.eurekalert.org/newsportal/WPI
Main WPI program site:  www.jsps.go.jp/english/e-toplevel

 

Advanced Institute for Materials Research (AIMR)
Tohoku University

Establishing a World-Leading Research Center for Materials Science

AIMR aims to contribute to society through its actions as a world-leading research center for materials science and push the boundaries of research frontiers. To this end, the institute gathers excellent researchers in the fields of physics, chemistry, materials science, engineering, and mathematics and provides a world-class research environment.

 SPACE/COSMOS

Chang’e-6 lunar samples reveal 2.83-billion-year-old basalt with depleted mantle source



Chinese Academy of Sciences Headquarters
Landing site of the Chang’e-6 mission on the Moon’s far side 

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Fig. 1 Landing site of the Chang’e-6 mission on the Moon’s far side

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Credit: Image by GIGCAS




The Moon has a global dichotomy, with its near and far sides having different geomorphology, topography, chemical composition, crustal thickness, and evidence of volcanism.
To better understand this dichotomy, Professor XU Yigang’s team from the Guangzhou Institute of Geochemistry of the Chinese Academy of Sciences investigated lunar soil samples from the far side South Pole-Aitken (SPA) Basin of the Moon returned by the Chang’e-6 mission.
Their work was published in Science on Nov. 15.
“The samples returned by Chang’e-6 provide a best opportunity to investigate the lunar global dichotomy,” said Professor XU.
Volcanic eruptions flooded parts of the surface with lava, producing rocks known as mare basalts, which are more common on the near side, where they cover ~30% of the surface compared to 2% of the far side. It is obvious that to investigate the lunar global dichotomy, samples from both the near and far sides are needed.
The Chang’e-6 lunar soils contain two types of mare basalts: low-Ti and very low-Ti (VLT). The predominant low-Ti basalt represents the local basalt unit around the landing site, whereas the VLT basalt possibly came from the unit to the east of the landing site (Figure 1B).
The high-precision Pb-Pb dating of Zr-bearing minerals and Rb-Sr dating of plagioclase and late-stage mesostasis of the low-Ti basalt yield consistent isochron ages of 2.83 Ga (Figure 2), indicating that “young magmatism also exits on the lunar far side,” according to the study.
Compared to the near side samples returned by the Apollo and Chang’e-5 missions, the Chang’e-6 low-Ti basalt has a low μ value and 87Sr/86Sr and a very high εNd value (Figure 3), suggesting a very depleted mantle source.
Crustal thickness has been suggested as a key factor in accounting for asymmetry in the abundance of volcanism between the lunar near side and far side. However, this model has been questioned since the SPA basin on the far side, which has an anomalously thin crust, appears deep and significantly underfilled by volcanism.
Based on the investigation of Chang’e-6 low-Ti basalt, XU’s team suggested that the composition of the mantle source is another important factor controlling the generation of lunar volcanic activity.
“Although the SPA basin has a thin crust, the depleted and refractory mantle source beneath the SPA basin hinders partial melting to a large degree,” said XU.
This work also provides an additional calibration point at 2.83 Ga for the lunar crater chronology and implies a constant impact flux after 2.83 Ga. This newly calibrated chronology model improves the age estimation tool based on crater statistics for both the Moon and other terrestrial bodies, and also has additional implications for the evolution of lunar impactors, potentially related with early planet migration in the early Solar System.
This work was financially supported by the Chinese Academy of Sciences and the lunar research program of GIGCAS.

Figure 2 The two types of basalts in Chang’e-6 soils and isochrons of the Chang’e-6 low-Ti basalt.

Figure 3 Initial Pb and Sr-Nd isotopes of lunar basalts.

Figure 4 Incorporating the Chang’e-6 landing site into a lunar crater chronology model.

Credit

Image by GIGCAS

 

Rainforest protection reduces the number of respiratory diseases



Study by the University of Bonn shows that deforestation in the Amazon region is also detrimental to human health


University of Bonn





Rainforest protection is not only good for biodiversity and the climate – it also noticeably improves the health of humans who live in the corresponding regions. This is the conclusion drawn by a current study by the University of Bonn and the Universidade Federal de Minas Gerais in Brazil. In this, the researchers show that measures to combat slash-and-burn techniques significantly reduce the concentration of particulate matter in the air. The number of hospital stays and deaths due to respiratory diseases thus also decreases. The results have been published now in the journal Nature Communications, Earth & Environment.

In 2019, almost 70,000 square kilometers of forest were burned in the Amazon region – this equates to an area the size of Bavaria. Natural fires are normally rare in the damp conditions that prevail there. However, major landowners and landgrabbers often clear huge areas to use them as pastures or for arable farming.

This overexploitation of Brazil’s green lung destroys the habitats of many species of flora and fauna and also accelerates climate change. However, the current study also takes into account another consequence that is often not given enough attention: The smoke generated during the fires is an important trigger of respiratory and cardiovascular diseases.

“We have thus investigated to what extent forest protection measures affect the health of people living in the corresponding regions,” explains Yannic Damm. The scientist is a member of Prof. Dr. Jan Börner’s research group at the Institute for Food and Resource Economics (ILR) at the University of Bonn. He conducted the study together with his ILR colleague Dr. Nicolas Gerber and with Prof. Dr. Britaldo Soares-Filho from the Universidade Federal de Minas Gerais in Brazil.

How does forest protection affect human health?

The Amazon region of Brazil is divided into two different zones: The legally defined Amazon, which follows the borders of the Amazonian states, and what is known as the Amazon biome, which follows the original forest boundary. “Between 2004 and 2010, a whole range of laws were adopted to curb the ongoing deforestation throughout the Amazon region,” says Damm. “However, in our study, we concentrated on three measures that exclusively apply within the Amazon biome and came into force from 2006.”

The most well-known of these three measures is presumably the Soy Moratorium. In this, globally operating trading companies agreed to no longer purchase soy grown in freshly deforested areas. “As a result, deforestation pressure has measurably reduced,” explains Damm. However, the moratorium (along with the other two resolutions investigated) only applies to the Amazon biome, but not to the neighboring Legal Amazon region with a lower protection status.

The researchers made use of this fact: They compared several hundred municipalities on the biome border with neighboring regions that lay outside of this border and to which the three measures did not, therefore, apply. “In this way, we were able to identify what effect the increased protection efforts had on public health,” highlights Damm. The group evaluated, among other things, the particulate matter pollution in the air, and analyzed the reasons why people in the investigated regions were taken to hospital or died.

Protective measures save 680 human lives per year

The effects of forest protection measures on each of these parameters were clear. The concentration of fine dust particles in the air fell in all of the investigated regions after 2006. However, this decrease was almost 7 percent higher in the municipalities within the biome borders. The number of hospital treatments and deaths due to respiratory and cardiovascular diseases also fell. Around four million men, women, and children live in the regions in which the three measures were established. The researchers estimate that around 680 human lives in this group were saved each year thanks to the reduced air pollution.

“Our study has two messages,” explains ILR researcher Prof. Dr. Jan Börner, who is also a member of the Transdisciplinary Research Area (TRA) Sustainable Futures and the Cluster of Excellence “PhenoRob” at the University of Bonn. “Namely, firstly, that the destruction of the rainforest can be successfully curbed. And, secondly, that this benefits not only the diversity of species and the global climate but also very specifically and very quickly the local population. This is an aspect that is still given too little consideration when assessing protective measures.”

Participating institutions and funding:

The University of Bonn and the Universidade Federal de Minas Gerais in Brazil took part in the study. The work was supported with funding from the German Research Foundation (DFG), the German Federal Ministry of Education and Research (BMBF), and the EU research and innovation program Horizon Europe.

 

Recycling batteries with citric acid



Highly efficient recycling process for NCM lithium-ion batteries



Wiley




A simple, highly efficient, inexpensive, and environmentally friendly process could provide a viable pathway for the sustainable recycling of depleted lithium-ion batteries (LIBs): No chemicals beyond citric acid need to be added to leach out and separate over 99 % of the lithium, nickel, cobalt, and manganese metals contained in NCM batteries. The resulting recycled material can be directly converted into NCM electrodes, reports a research team in the journal Angewandte Chemie.

From smartphones to electric vehicles, lithium-ion batteries are everywhere in our daily lives. They are also an important component of our transition to renewable energy, as they are used to store excess solar and wind energy and send it back into the power grid on demand. The downside is that their limited lifespan results in vast numbers of spent LIBs that contain dangerous heavy metals and other hazardous materials. In addition, metal resources are being depleted.

Most recycling processes suffer from high energy usage, high emissions, and limited or low-quality recovered material. Or they require very large amounts of chemicals, are complicated and expensive, and produce toxic gases and run-off. Leaching with biocompatible acids like citric acid is one alternative to these processes. However, conventional processes (chelation-gel process) require a significant excess of the acid, and the pH value must constantly be adjusted with ammonia—complicated and not very environmentally friendly.

A team at China University of Mining and Technology (Beijing), Fuzhou University, Beijing University of Chemical Technology, and Tsinghua University, Shenzhen (China) led by Guangmin Zhou and Ruiping Liu has now developed a novel citric-acid-based method for the leeching, separation, and reclamation of metals from NCM cathodes. NCM is a mixed oxide containing nickel, cobalt, and manganese in a lamellar structure. Lithium ions are enclosed between the layers.

The trick to their method: Instead of leeching with an excess of citric acid like conventional methods, they use a relatively small amount. Because of this, only two of the three acid groups in the citric acid dissociate. The released protons break up the lithium-oxygen bonds, releasing lithium ions from the NCM into the solution. Bonds between the other metal ions and the oxygen ions are also broken. Nickel, cobalt, and manganese enter the solution, where they are bound into stable complexes by the citric acid anions. The third acid group of the citric acid then reacts with the hydroxyl group on the same molecule. A ring closure occurs in an intramolecular esterification (Fischer lactonization) reaction. This facilitates the reaction of the intermediates with each other to make a polyester, which gels into solid particles that can easily be separated out. Energy consumption and CO2 emissions are significantly less than in conventional hydrometallurgical recycling processes.

The gel can subsequently be heated to burn off the organic fragment. This results in a new NCM lamellar framework with included lithium ions, which can be used as a high-quality electrode material.

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About the Author

Dr Ruiping Liu is Professor at the School of Chemical and Environmental Engineering at China University of Mining and Technology (Beijing). His major research mainly focused on the synthesis of functional materials, and their applications in batteries and catalysts.

 

One or many? Exploring the population groups of the largest animal on Earth




University of Washington




 

Hunted nearly to extinction during 20th century whaling, the Antarctic blue whale, the world’s largest animal, went from a population size of roughly 200,000 to little more than 300. The most recent estimate in 2004 put Antarctic blue whales at less than 1% of their pre-whaling levels.

But is this population recovering? Is there just one population of Antarctic blue whales, or multiple? Do these questions matter for conservation?

A team led by Zoe Rand, a University of Washington doctoral student, tackles these questions in a study, published Nov. 14 in Endangered Species Research. Building on the last assessment of Antarctic blue whales in 2004 and using old whaling records, which were surprisingly detailed, Rand and her colleagues investigated if the Antarctic blue whales consist of different populations or are one big circumpolar population. Study co-authors are Trevor Branch, a UW professor of aquatic and fishery sciences, and Jennifer Jackson from the British Antarctic Survey.

Antarctic blue whales are listed as an endangered species, and understanding their population structure is essential for their conservation. Conservation at the population-level increases biodiversity, which helps the species adapt better to environmental changes and increases chances of long-term survival.

During the whaling years, biologists began the Discovery Marking Program. Foot-long metal rods with serial numbers were shot into the muscles of whales. When these whales were caught, the metal rod was returned, and the whale’s size, sex, length and location where it was caught was noted. Looking at where whales were marked compared to where they were caught could shed valuable insight into the movement of Antarctic blue whales, but these data have never been used before to look at population structure.

In this new study, this historical data were used alongside contemporary survey data in Bayesian models to calculate inter-annual movement rates among the three ocean basins that make up the Southern Ocean — Atlantic, Indian and Pacific — which make up the feeding grounds for Antarctic blue whales. The team found frequent mixing among the ocean basins, suggesting that whales do not return to the same basin every year. This points to Antarctic blue whales being one single circumpolar population in the Southern Ocean.

These results are consistent with studies of Antarctic blue whale songs, heard throughout the Southern Ocean. Only one song type has been recorded among the Antarctic blue whales. In comparison, pygmy blue whales have five different songs corresponding to five different populations. These results are also consistent with genetic studies, which found that Antarctic blue whales are more closely related than would be expected if they were separate populations.

This study is the first time that historical mark-recovery data from the Discovery Marking Program has been analyzed using modern quantitative methods. These data exist for many other hunted whale species, such as fin and sei whales, so the new study’s methods could provide a framework for similar analyses for those whale species too.

There is still a lot scientists don’t know about the Antarctic blue whale. Even though they do not appear to be separated geographically on their feeding waters in different ocean basins, they could still have distinct population structures based on differences in breeding habitats or the timing of migration. However, almost nothing is known about Antarctic blue whale breeding behavior, according to the researchers. Using historical data from whaling alongside contemporary data — such as satellite tagging and photo-identification — remains scientists’ best hope for uncovering the secrets of the largest animal on Earth.

The research was funded by the International Whaling Commission’s Southern Ocean Research Partnership.

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For more information, contact Rand at zrand@uw.edu and Branch at tbranch@uw.edu.

Text by Niamh Owen-McLaughlin.

 

USF study confirms Egyptians drank hallucinogenic cocktails in ancient rituals



New paper’s findings reveal a mix of psychedelic drugs, body fluids and alcohol likely used for fertility rituals




University of South Florida

Vertical of Bes mug 

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University of South Florida scholar Davide Tanasi holds a 3D-generated replica of the Egyptian Bes mug.

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Credit: Cassidy Delamarter




TAMPA, Fla. (Nov. 15, 2024) – A University of South Florida professor found the first-ever physical evidence of hallucinogens in an Egyptian mug, validating written records and centuries-old myths of ancient Egyptian rituals and practices. Through advanced chemical analyses, Davide Tanasi examined one of the world’s few remaining Egyptian Bes mugs.

Such mugs, including the one donated to the Tampa Museum of Art in 1984, are decorated with the head of Bes, an ancient Egyptian god or guardian demon worshiped for protection, fertility, medicinal healing and magical purification. Published Wednesday in Nature’s Scientific Reports, the study sheds light on an ancient Egyptian mystery: The secret of how Bes mugs were used about 2,000 years ago.

“There’s no research out there that has ever found what we found in this study,” Tanasi said. “For the first time, we were able to identify all the chemical signatures of the components of the liquid concoction contained in the Tampa Museum of Art’s Bes mug, including the plants used by Egyptians, all of which have psychotropic and medicinal properties.”

The presence of Bes mugs in different contexts over a long period of time made it extremely difficult to speculate on their contents or roles in ancient Egyptian culture.

“For a very long time now, Egyptologists have been speculating what mugs with the head of Bes could have been used for, and for what kind of beverage, like sacred water, milk, wine or beer,” said Branko van Oppen, curator of Greek and Roman art at the Tampa Museum of Art. “Experts did not know if these mugs were used in daily life, for religious purposes or in magic rituals.”

Several theories about the mugs and vases were formulated on myths, but few of them were ever tested to reveal their exact ingredients until the truth was extracted layer by layer.

Tanasi, who developed this study as part of the Mediterranean Diet Archaeology project promoted by the USF Institute for the Advanced Study of Culture and the Environment, collaborated with several USF researchers and partners in Italy at the University of Trieste and the University of Milan to perform chemical and DNA analyses. With a pulverized sample from scraping the inner walls of the vase, the team combined numerous analytical techniques for the first time to uncover what the mug last held.

The new tactic was successful and revealed the vase had a cocktail of psychedelic drugs, bodily fluids and alcohol – a combination that Tanasi believes was used in a magical ritual reenacting an Egyptian myth, likely for fertility. The concoction was flavored with honey, sesame seeds, pine nuts, licorice and grapes, which were commonly used to make the beverage look like blood.

“This research teaches us about magic rituals in the Greco-Roman period in Egypt,” Van Oppen said. “Egyptologists believe that people visited the so-called Bes Chambers at Saqqara when they wished to confirm a successful pregnancy because pregnancies in the ancient world were fraught with dangers. So, this combination of ingredients may have been used in a dream-vision inducing magic ritual within the context of this dangerous period of childbirth.”

“Religion is one of the most fascinating and puzzling aspects of ancient civilizations,” Tanasi said. “With this study, we’ve found scientific proof that the Egyptian myths have some kind of truth and it helps us shed light on the poorly understood rituals that were likely carried out in the Bes Chambers in Saqqara, near the Great Pyramids at Giza.”

Close-up image of a 3-D replica of the Egyptian Bes mug used in the study.

Credit

Cassidy Delamarter

The Bes mug is on display now at the Tampa Museum of Art and can be viewed in the exhibition, “Prelude: An Introduction to the Permanent Collection.” View a 3D model of the Bes mug produced by the USF Institute for Digital Exploration.

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Gathering a sample of the Bes [VIDEO] | 

Univeristy of South Florida scholar Davide Tanasi gathers a sample from the Bes mug.

3-D scanning the Bes mug [VIDEO] | 


University of South Florida scholar Davide Tanasi creates a 3-D replica of the Egyptian Bes mug used in the study.

ty of South Florida scholar Davide Tanasi creates a 3-D replica of the Egyptian Bes mug used in the study.

University of South Florida scholar Davide Tanasi creates a 3-D replica of the Egyptian Bes mug used in the study.