High-capacity Li-metal battery with improved rate-performance and stability
A KERI research team developed a one-dimensional Li-confinable porous hollow carbon host. Improved Li deposition/dissolution efficiency under high-rate testing conditions ... published as a cover paper in ACS Nano.
Peer-Reviewed PublicationIMAGE: A 1D LI-CONFINABLE HOST WITH A POROUS CARBON SHELL AND LITHIOPHILIC AU NANOPARTICLES IN THE CORE SHOWS IMPROVED LI REVERSIBILITY AT HIGH RATES OWING TO THE FACILE LI+ TRANSPORT AND THE LI DENDRITE SUPPRESSION BY STORING LI AT THE CORE PLACE, REVEALING THE IMPORTANCE OF STRUCTURAL DESIGN FOR LI STORAGE. view more
CREDIT: KOREA ELECTROTECHNOLOGY RESEARCH INSTITUTE
A study of Li-metal batteries by the research team led by Dr. Byung Gon Kim at Next-Generation Battery Research Center of Korea Electrotechnology Research Institute (KERI, Acting President Nam-Kyun Kim) was published as a cover paper in a renowned international journal.
While the current Li-ion batteries generate energy by taking Li-ions in and out of the graphite anode based on the intercalation mechanism, the Li-metal battery does not rely on this bulky and heavy graphite but uses metallic Li itself as the anode. As the Li-metal shows 10 times higher theoretical capacity (3,860 mAh/g) than graphite (372 mAh/g), it has steadily gained much attention from areas that need high-capacity batteries, such as electric vehicles and energy storage systems.
Despite this advantage, Li can grow in the shape of a tree branch, called Li dendrite, if it is not uniformly and effectively stored when cycling process, leading to large volume expansion of electrode, which in turn may shorten the battery’s cycle life and cause safety issue such as fire and explosion triggered by internal short-circuits.
To tackle this issue, KERI developed 1D Li-confinable porous carbon structure with a hollow core, and a small number of gold nanoparticles with Li affinity were added to the hollow core. Here, the gold controls the growth direction of Li by preferentially reacting with Li, thereby inducing Li deposition inside the core. In addition, many nano-sized pores are formed in the shell part to improve the Li-ion movement toward the core space.
A major challenge observed in the existing hollow core-shell Li host was the Li deposition on the conductive carbon shell, not inside the core, under high-rate charging conditions. Therefore, the KERI team introduced many nano-sized pores to the shell, and achieved significantly improved coulombic efficiency without Li dendrite growth even under a high-current testing condition of 5 mA/cm2.
Dr. Kim’s team collaborated with Prof. Janghyuk Moon at Chung-Ang University for theoretical validation of the effectiveness of this material’s design, and the simulation results showed that the reduced Li ion diffusion length by the shell pores and improved Li affinity by the gold nanoparticles kept Li deposition inside the structure even under high-current charging condition. Moreover, the designed Li host showed excellent cycling performance of over 500 cycles1) under a high current density of 4C rate2) (82.5% capacity retention). It is also notable that this technology meets practicality because the team used the electrospinning technique with advantages in mass production for material synthesis.
“Despite the merit of high capacity, the Li-metal batteries have many hurdles to be overcome for commercialization mainly due to stability and safety issues,” said Dr. Kim. And Dr. Kim also said, “Our study is invaluable in that we developed a technique for mass production of Li-metal reservoir with high coulombic efficiency for fast-rechargeable Li-metal batteries.”
This study by the KERI research team was published as a supplementary cover paper in the August edition of ACS Nano, one of the leading SCIE journals in materials science published by the American Chemical Society. The journal’s Impact Factor is 18.027, and top 5.8% of all journals in its category.
This study was funded by the National Research Foundation’s Technology Development Program to Solve Climate Changes and the KERI Primary Research Program. The team plans to continue with the pursuit of the commercialization of Li-metal battery by, for example, developing functional electrolytes to ensure the stable deposition and dissolution of metallic Li.
KERI is a government-funded research institute dedicated to electricity under the National Research Council of Science & Technology (NST) of the Ministry of Science and ICT. Dr. Kim is an associate professor at University of Science and Technology (UST) KERI Campus.
1) Battery cycle: The number of charge/discharge cycles that can be achieved before the battery reaches the end of its service life or commercial value. For example, a battery with a 500 battery cycle count will lose a half of its energy capacity after 500 cycles of charging/discharging, losing its commercial value. Electric vehicles are so sensitive about the operating mileage that the battery packs are often replaced when they have lost only 20% of their capacity.
2) C-rate: 1C-rate refers current which can charge or discharge the cell in 1 hour. For example, 0.5C is a two-hour discharge and 0.2C is a 5-hour discharge.
JOURNAL
ACS Nano
ARTICLE TITLE
One-Dimensional Porous Li-Confinable Hosts for High-Rate and Stable Li-Metal Batteries
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