Sunday, October 22, 2023

 

Research shows how airline pricing really works


A new paper coauthored by Olivia Natan of Berkeley Haas and published in The Quarterly Journal of Economics peers into the black box of airline pricing and finds some surprises.


Peer-Reviewed Publication

UNIVERSITY OF CALIFORNIA - BERKELEY HAAS SCHOOL OF BUSINESS




By Dylan Walsh

Buy your ticket on a Tuesday. Search in your browser’s incognito mode. Use a VPN to pretend you live in Suriname.

“There are so many hacks out there for finding cheaper airline tickets,” says Olivia Natan, an assistant professor of marketing at the Haas School of Business. “But our data shows many of these beliefs are wrong.”

With four colleagues—Ali Hortaçsu and Timothy Schwieg from the University of Chicago, Kevin Williams from Yale, and Hayden Parsley from the University of Texas at Austin—Natan looked deeply into the structure and processes behind how prices are set at a major U.S. airline. The system that she found, which is representative of airlines around the world, was strikingly at odds with what many economists would expect—and most consumers assume.

“We initially didn’t know how to rationalize the things we were seeing,” she says.

Substituting convenience for price

Consider fruit jam at the grocery store. Consumers have many options. If a company raises the price on its strawberry jam, one might fairly assume that this would affect sales of both strawberry and neighboring raspberry jam, since consumers can substitute one for another.

The same can happen with plane tickets: When people visit a website such as Google Flights or Kayak and search for a ticket, a wide range of different flights from the same airline appear. Travelers tend to make selections that balance convenience and price: The price of one flight might push people to select a slightly less convenient but cheaper flight.

“But the systems airlines use don’t consider this kind of substitution,” Natan says.  They set the prices of seats on each individual flight on a given route separately, “even though changing the price on one flight will affect the way people think about all their options.”

A small menu of pre-set prices

Perhaps most surprisingly, airlines also don’t directly incorporate the prices of their competitors in their automated price-setting. Typically, if one airline cut its prices, one would expect other firms to do the same. If they don’t, this dampens the benefits of a competitive market.

Setting prices of each product separately without considering substitution, Natan explains, is the result of a specific pricing heuristic—or decision-making shortcut—that airlines use called Expected Marginal Seat Revenue-b, or EMSRb. This shortcut is widely used because it is fast enough to set prices for hundreds of thousands of flights daily, and it allows airlines to reserve some seats to sell at higher prices.

The use of EMSRb, the researchers show, results in another outcome that consumers may not expect. Despite how it may appear when looking for flights, airlines have a fixed and relatively small number of prices that they assign to tickets on each flight. Unlike other consumer sectors, where pricing can be adjusted and targeted down to the penny, airlines operate with large gaps between each possible price—sometimes upwards of $100. They may sell the first 30 economy tickets at the lowest price, and then the next 30 tickets at the next possible price, and so on.

“Airline tickets are sold through global distribution systems that make sure a travel agent in Wichita or Miami sees the same price as you do on your computer at home,” Natan says. This system emerged from an industry alliance to facilitate inventory management across many channels. Other businesses in the travel sector, such as hotel rooms, cruises, trains, and car rentals do the same.

The downside is that airline ticket prices are relatively unresponsive to real-time changes in opportunity costs, as the next discrete fare is often a significant jump up. The researchers found that even if the airline would like to increase the price by $100—half the price of an average one-way ticket—they only do so about 20% of the time, since no fare is available at that price.

Today, airlines are starting to experiment with what’s known as “continuous revenue management,” which would, for instance, assign 100 different prices to a flight with 100 seats. “That would make pricing significantly more variable,” Natan says, “but even that would not be the kind of targeting that many consumers assume airlines use.”

Lack of coordination across departments

One of the strangest discoveries from the research relates to the process airlines use to set their prices. To an economist, Natan explained, there is never a reason that firms would not raise prices if the increase assures an increase in revenue. But the set of possible prices chosen by the pricing team nearly always includes an option which is too low, even by their internal estimates.

The pricing team’s work is made difficult by having to choose an entire menu of discrete prices, “but we found they could make more money today by selling fewer tickets at higher prices and not foreclose future opportunities. In practice, they choose the menu of prices without using their internal demand predictions,” Natan says.

Interestingly, the revenue management team corrects much of this underpricing before it ever reaches consumers. After prices are filed and before tickets go on sale, this team makes demand forecasts that determine final prices. These forecasts are routinely inflated, reducing the number of underpriced tickets shown to consumers by roughly 60%.

“We find that these prices are a consequence of teams from different departments choosing the best pricing inputs when they are unable to  coordinate,” Natan says “This may result in lower revenue, but in practice our solution could not be implemented.” Two other possibilities as to why airlines don’t only focus on short-term revenue, she speculated, are either to build customer loyalty or to avoid regulatory scrutiny.

Over the next several years, Natan says, airlines may start to adopt more dynamic pricing platforms, and non-business travelers may benefit from these changes. But for now, the hunt for an undiscovered trick to find lower fares is largely futile. What is clear is that it's wise not to wait until the last minute. “What I can say is that prices do go up significantly 21, 14, and seven days before a flight,” Natan says. “Just buy your ticket before then.”

Note: This article has been updated from the original version published October 12, 2023.

Read the full paper:

Organizational Structure and Pricing: Evidence from a Large U.S. Airline
By Ali Hortaçsu, Olivia Natan, Hayden Parsley, Timothy Schwieg, and Kevin Williams
The Quarterly Journal of Economics, Sept. 27, 2023

 

 

UK’s first local Net Zero Carbon planning policy likely to drive more efficient buildings and cut energy bills, review shows


University of Bath researchers have analyzed the first six months of a new net zero carbon planning policy in Bath & North East Somerset, finding that heat pumps and solar panels on new developments are likely to be crucial to achieving its goals


Reports and Proceedings

UNIVERSITY OF BATH

Bath city skyline 

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THE NEW PLANNING POLICY MAKES BATH AND ITS SURROUNDINGS, KNOWN FOR HISTORIC ARCHITECTURE, AN IMPORTANT TESTBED FOR FUTURE NATIONAL REGULATIONS

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CREDIT: NIC DELVES-BROUGHTON / UNIVERSITY OF BATH





The UK’s first Net Zero Carbon planning policy is likely to establish significant carbon savings in new buildings and reduce energy bills for occupants, a study has found.

A review led by University of Bath researchers into the first six months of the UK’s first Net Zero Carbon construction policy, implemented by Bath & North East Somerset Council (B&NES), has found that most planning applicants broadly support the intentions of the policy, while highlighting concerns about increased planning and construction costs, and awareness of the scheme.

Introduced in January 2023, the new policy is the first of its kind to be adopted by a local authority and goes beyond the current UK Building Regulations. It covers both the operational or day-to-day emissions (of heating, powering and cooling), as well as the ‘embodied’ emissions that are released in a building’s construction and maintenance. The policy requires that all new residential and major non-residential building developments achieve net zero operational energy, by meeting ambitious energy consumption targets and matching consumption with on-site renewables with offsetting allowed only in exceptional circumstances.

All major developments must also demonstrate an embodied carbon value below a threshold value – something not required in the current national regulations - with no offsetting permitted.

The report authors found that every compliant application submitted during the review period included solar photovoltaics and heat pumps – indicating a strong consensus that currently, they are key technologies in efforts to achieve net zero.

The new framework makes Bath and its surroundings, known for historic architecture, an important testbed for future national regulations and local planning policies.

Contributors to the report include planning staff from B&NES, representatives from the South West Net Zero Hub, Chapter 2 Architects and the sustainability consultancy Bioregional.

Researchers from the University of Bath’s Department of Architecture & Civil Engineering studied every planning application made to B&NES between the introduction of the policy in January 2023 and July 2023, before following up with applicants with a questionnaire. They found that more than half (55%) of planning applications were non-compliant, primarily due to a lack of awareness of the policy.

Applicants were unanimous in their concern around the cost of meeting the new guidelines, with costs attributed to hiring additional consultants, constructing higher performing buildings and generating renewable energy on site.

Dr Will Hawkins, principal investigator of the report, is a lecturer in the University of Bath’s Department of Architecture & Civil Engineering. He said: “Buildings directly account for a quarter of the UK’s greenhouse gas emissions, so early pioneers like Bath & North East Somerset Council can have big impacts both locally and further afield. Our collaboration aims to maximise the benefits for builders, developers and building occupiers, as well as the environment.

“We found evidence that this policy is likely to make all new buildings much more energy efficient and will also boost the introduction and take-up of renewables, compared to the previous guidelines. This isn’t fully proven yet as the buildings are still to be built, but the evidence available so far is very encouraging in terms of carbon reduction.”

Councillor Matt McCabe, B&NES Cabinet Member for Built Environment and Sustainable Development, said: “The changes we made, through the adoption of the Local Plan Partial Update (LPPU) put Bath & North East Somerset at the forefront nationally with policies related to the climate and ecological emergencies.

“I am proud that the council was the first Local Planning Authority (LPA) in England to have an adopted Local Plan policy requiring a net zero energy based requirement for new housing and we are the first in the West of England to adopt a biodiversity net gain (BNG) policy. This is the bedrock for the council’s climate emergency ambitions and I am encouraged by the outcome of the review and its findings.”

Dr Elli Nikolaidou, author of the report and building engineer in the South West Net Zero Hub, added: “We hope this report will inform the future development and implementation of effective net zero carbon construction policies in B&NES and elsewhere. We welcome any feedback that could help us expand this study and ultimately improve local planning policies.”

Other issues uncovered in the study include questions around the achievability of air permeability targets, lack of transparency in applications, and difficulties in matching renewable generation to demand in tall buildings.

The authors are now seeking to carry out a longer-term study, which they say is needed to track the evolving industry response, quantify the real emission savings through construction and occupation, and engage with stakeholders to support the policy’s implementation, further development, and wider impact. This would include investigating the policy response from a social science perspective and investigating a varied sample of key projects over the full cycle of construction and occupation to assess compliance and measure real emissions and energy use.

B&NES planning policy in detail

Adopted in January 2023, the Bath & North East Somerset Council planning policy is the first in the UK to require:

  • All new residential and major non-residential buildings must achieve net zero operational energy. Ambitious energy consumption and building performance targets must be met and matched by on-site renewable generation. Only where this is demonstrably infeasible can the remainder be offset through a financial contribution.
  • Major developments must demonstrate an embodied carbon below a threshold value. This covers a building’s substructure, superstructure and finishes, and includes material production, transportation and construction to the ‘practical completion’ of the building.

The report, Pioneering Net Zero Carbon Construction Policy in Bath & North East Somerset, is available at https://doi.org/10.15125/BATHRO-297388880.

Parties interested in collaborating with the review team are encouraged to contact Dr Will Hawkins at wh604@bath.ac.uk.

ENDS

 

Notes

For interview requests or more information, contact Wil McManus at wem25@bath.ac.uk or on +44(0)1225 385 798.

To download an image, visit: https://tinyurl.com/45z9zrw9 Credit ‘Nic Delves-Broughton / University of Bath’

The University of Bath 

The University of Bath is one of the UK's leading universities for high-impact research with a reputation for excellence in education, student experience and graduate prospects. 

We are named ‘University of the Year’ in The Times and The Sunday Times Good University Guide 2023, and ranked among the world’s top 10% of universities, placing 148th in the QS World University Rankings 2024. We are ranked 5th in the UK in the Complete University Guide 2024, 6th in the Guardian University Guide 2024 and 8th in the The Times and Sunday Times Good University Guide 2024. 

Bath is rated in the world’s top 10 universities for sport in the QS World University Ranking by Subject 2023. We produce some of the world’s most job-ready graduates and were named University of the Year for Graduate Jobs by the Daily Mail University Guide 2024, as well as ranking as one of the world’s top 90 universities for employer reputation according to the QS World University Rankings 2024.

Research from Bath is helping to change the world for the better. Across the University’s three Faculties and School of Management, our research is making an impact in society, leading to low-carbon living, positive digital futures, and improved health and wellbeing. Find out all about our Research with Impact: https://www.bath.ac.uk/campaigns/research-with-impact

LIST to coordinate Horizon Europe project on next generation of 6G mobile networks


The €4m project will play a pivotal role in shaping the future of wireless communication in Europe

Business Announcement

LUXEMBOURG INSTITUTE OF SCIENCE AND TECHNOLOGY

6G-TWIN 

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6G-TWIN LOGO

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CREDIT: LIST




The Luxembourg Institute of Science and Technology (LIST) will coordinate a project on 6G mobile networks funded by the Smart Networks and Services Joint Undertaking (SNS JU) under the Horizon Europe programme. Entitled 6G-TWIN, the project is one of the 27 new research and experimentation initiatives selected from the second SNS JU call for proposals, which will all start operating from January 1, 2024. Established by the European Commission in 2021, SNS JU serves as a foundation for fostering the growth of intelligent communication components, systems, and networks, which play a crucial role in constructing a top-tier European supply chain for cutting-edge 5G and upcoming 6G technologies.

Beyond 5G

The rapid integration of digital technology across industries like transportation and manufacturing has boosted the need for efficient communication and computing services. To meet this, innovative approaches for 6G architecture are crucial, aiming to go beyond current 5G capabilities.

“Each generation of mobile technology takes roughly a decade to evolve from conception to commercial deployment,” explains Sébastien Faye, 6G-TWIN Project Coordinator.  “Starting from the first generations, which brought basic cellular connectivity, through 5G, which facilitates revolutionary applications like connected and automated mobility, each iteration introduces new capabilities to meet a demand that is continually growing. Networks are becoming increasingly complex and distributed, requiring a large variety of technologies to operate. With 6G, which is now on the horizon for around 2030, it is essential to design, experiment and standardize new network architectures with more intelligence and automation - which is what we will be proposing in this project.”

European 6G roadmaps prioritize an AI-native management system for complex networks. These networks need to be sustainable, energy-efficient, and adaptable to various services and business models. Establishing a consistent unified communication and computing architecture requires unconventional methods, along with collaboration among standardization groups and industry leaders for practical market integration.

Leveraging AI for next-generation 6G architecture

To achieve this, the 6G-TWIN consortium “will explore the concept of Network Digital Twinning (NDT) and its integration into future 6G systems”, says Faye. Creating a real-time digital replica of the physical network infrastructure (i.e., NDTs) means creating a sandbox in which it is possible to train models and test different scenarios before deploying them on physical network controllers. “6G will enable real-time interaction between physical networks and these digital copies, with the aim of optimizing various parameters, anticipating failures, improving energy efficiency and so on,” he adds, “thus paving the way for highly efficient and intelligent networks.”

The project also includes plans to create demonstrators that validate the concepts developed, adds Faye. These demonstrators encompass teleoperated driving and energy-efficient network distribution. “By exploring these real-world applications, the project will not only contribute to the theoretical advancement of 6G but also demonstrate its practical feasibility – thanks to a wide range of expertise from the 11 project partners.”

The 6G-TWIN consortium is made up of multiple partners, ranging from universities and research centres (IMEC, Politecnico di Bari, Technische Universität Dresden, Université de Bourgogne) to SMEs (Accelleran, Research to Market Solution France, Ubiwhere) and large industrial entities (Ericsson Araştırma Geliştirme ve Bilişim Hizmetleri A.Ş., Proximus Luxembourg, VIAVI Solutions). From Luxembourg, the collaboration includes Proximus Luxembourg/Telindus, with whom LIST already has a collaboration agreement on the development of business use-cases based on advanced connectivity. With a total grand budget of €4 million over three years, this initiative exemplifies the European Commission's commitment to fostering innovation and research that will shape the future of wireless communication, and, within LIST, another step towards the creation of a strong centre of excellence around Digital Twin Technologies.

 

Ancient sea monster remains reveal oldest mega-predatory pliosaur


Peer-Reviewed Publication

UPPSALA UNIVERSITY

Lorrainosaurus - Life reconstruction 

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THE OLDEST MEGAPREDATORY PLIOSAUR, LORRAINOSAURUS, IN THE ANCIENT MIDDLE JURASSIC SEA THAT COVERED WHAT IS TO DAY NORTHERN FRANCE 170 MILLION YEARS AGO.

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CREDIT: JOSCHUA KNÜPPE




The fossils of a 170-million-year-old ancient marine reptile from the Age of Dinosaurs have been identified as the oldest-known mega-predatory pliosaur – a group of ocean-dwelling reptiles closely related to the famous long-necked plesiosaurs. The findings are rare and add new knowledge to the evolution of plesiosaurs. The study has been published in the journal Scientific Reports.

The fossils were found 40 years ago in north-eastern France. An international team of palaeontologists from the Naturkunde-Museum Bielefeld in Germany, the Institute of Paleobiology of the Polish Academy of Sciences in Warsaw, Poland, the Natural History Museum in Luxembourg and The Museum of Evolution at Uppsala University in Sweden have now analysed them and identified them as a new pliosaur genus: Lorrainosaurus.

Pliosaurs were a type of plesiosaur with short necks and massive skulls. They appeared over 200 million years ago, but remained minor components of marine ecosystems until suddenly developing into enormous apex predators. The new study shows that this adaptive shift followed feeding niche differentiation and the global decline of other predatory marine reptiles over 170 million years ago.

Lorrainosaurus is the oldest large-bodied pliosaur represented by an associated skeleton. It had jaws over 1.3 m long with large conical teeth and a bulky ‘torpedo-shaped’ body propelled by four flipper-like limbs.

Lorrainosaurus was one of the first truly huge pliosaurs. It gave rise to a dynasty of marine reptile mega-predators that ruled the oceans for around 80 million years,” explains Sven Sachs, a researcher at the Naturkunde-Museum Bielefeld, who led the study.

This giant reptile probably reached over 6 m from snout to tail, and lived during the early Middle Jurassic period. Intriguingly, very little is known about plesiosaurs from that time.

“Our identification of Lorrainosaurus as one of the earliest mega-predatory pliosaurs demonstrates that these creatures emerged immediately after a landmark restructuring of marine predator ecosystems across the Early-to-Middle Jurassic boundary, some 175 to 171 million years ago. This event profoundly affected many marine reptile groups and brought mega-predatory pliosaurids to dominance over ‘fish-like’ ichthyosaurs, ancient marine crocodile relatives, and other large-bodied predatory plesiosaurs”, adds Daniel Madzia from the Institute of Paleobiology of the Polish Academy of Sciences, who co-led the study.

Pliosaurs were some of the most successful marine predators of their time.

“Famous examples, such as Pliosaurus and Kronosaurus – some of the world’s largest pliosaurs – were absolutely enormous with body-lengths exceeding 10 m. They were ecological equivalents of today’s Killer whales and would have eaten a range of prey including squid-like cephalopods, large fish and other marine reptiles. These have all been found as preserved gut contents”, said senior co-author Benjamin Kear, Curator of Vertebrate Palaeontology and Researcher in Palaeontology at The Museum of Evolution, Uppsala University.

The recovered bones and teeth of Lorrainosaurus represent remnants of what was once a complete skeleton that decomposed and was dispersed across the ancient sea floor by currents and scavengers.

“The remains were unearthed in 1983 from a road cutting near Metz in Lorraine, north-eastern France. Palaeontology enthusiasts from the Association minéralogique et paléontologique d’Hayange et des environs recognised the significance of their discovery and donated the fossils to the Natural History Museum in Luxembourg”, said co-author Ben Thuy, Curator at the Natural History Museum in Luxembourg.

Other than a brief report published in 1994, the fossils of Lorrainosaurus remained obscure until this new study re-evaluated the finds. Lorrainosaurus indicates that the reign of gigantic mega-predatory pliosaurs must have commenced earlier than previously thought, and was locally responsive to major ecological changes affecting marine environments covering what is now western Europe during the early Middle Jurassic.

Lorrainosaurus is thus a critical addition to our knowledge of ancient marine reptiles from a time in the Age of Dinosaurs that has as yet been incompletely understood”, says Benjamin Kear.

Life-sized reconstruction of the head and jaws of the oldest megapredatory pliosaur, Lorrainosaurus.

The 1.3 m long lower jaw of Lorrainosaurus with a life-sized reconstruction of its head displayed in the Musée national d’histoire naturelle de Luxembourg.

CREDIT

Model By 10 Tons


Plants in the Cerrado combine at least two strategies to survive fire, study shows


Plant species native to the Brazilian savanna-like biome grow thick bark to protect their internal tissues and hide organs that assure resprouting below the ground, according to an article in Flora by researchers at São Paulo State University


Peer-Reviewed Publication

FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULO

Plants in the Cerrado combine at least two strategies to survive fire 

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DIFFERENT BELOW-GROUND ORGANS ANALYZED IN CERRADO SPECIES: (A) XYLOPODIUM IN STRYPHNODENDRON ROTUNDIFOLIUM; (B) XYLOPODIUM AND POSSIBLE TUBEROUS ROOT IN ANNONA CRASSIFLORA; (C) ROOT CROWN IN MICONIA ALBICANS; (D) WOODY RHIZOME IN HANDROANTHUS OCHRACEUS 

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CREDIT: MARCO ANTONIO CHIMINAZZO/UNESP




In an article published in the journal Flora, researchers at São Paulo State University (UNESP) in Brazil examine some of the strategies developed over eons of evolution by plants in the Cerrado, Brazil’s savanna-like biome, to protect themselves and resprout quickly after fire.

The article is commended by the journal as Highlighted Student Research. Its first author, Marco Antonio Chiminazzo, a PhD candidate at UNESP in Rio Claro, received funding from FAPESP for his master’s (19/21300-6) and PhD research (21/09269-9).  

The co-authors are Alessandra Fidelis, a professor in the Department of Biodiversity at the Rio Claro Institute of Biosciences (IBRC-UNESP); Aline Bombo, a postdoctoral fellow at the same institution, and Tristan Charles-Dominique, a researcher at the Paris Sorbonne and Montpellier University in France. All three are Chiminazzo’s thesis advisors.

“Fire plays an important role in the history of the Cerrado’s savanna-type vegetation. To survive fires, these plants have developed various strategies, which the different lineages have refined during a long evolutionary process,” Chiminazzo said. “We’ve known since we began studying the biome that the Cerrado’s plants have thick bark to protect their internal tissues. They also have a wide array of below-ground organs that enable them to resprout because they’re protected by being under the surface. However, these two strategies require plants to deploy a lot of resources. Our key question was whether they could do both at the same time – whether typical species of the Cerrado with below-ground organs were also able to produce significant amounts of above-ground bark.”

The researchers also set out to discover whether there were differences between clonal and non-clonal species in terms of bark production and bud protection and whether maximum height correlated with the ability to propagate clonally, given that clonal plants are generally smaller because their resources must be used to fuel both vertical and lateral growth.

“The first step was a review of the literature to identify woody species in the Cerrado whose below-ground organs and above-ground bark production rates had been described. We then went out into the field to dig and collect plants in areas of grassland with scattered shrubs [campo sujo] and dense woodland or shrubland [cerrado sensu stricto] in order to analyze their organs,” Chiminazzo said. The field trips were to the Santa Bárbara Ecological Station, an environmental protection unit in Águas de Santa Bárbara, São Paulo state.

“We grouped the species on the basis of clonality or non-clonality and of types of below-ground organ, especially woody rhizomes, which promote clonal growth, or xylopodia and root crowns, which do not,” he said.

By comparing below-ground organs and bark production rates, the authors of the study were able to show that plant species in the Cerrado can produce large amounts of bark (up to 0.9 millimeters per unit of growth) and at the same time develop below-ground organs that specialize in resprouting. In other words, they can protect themselves from fire by hiding a large proportion of their biomass below ground. 

“We also found a clear division between clonal species and species that occupy the same space throughout their life cycle [in a phenomenon termed on-spot persistence]. Specifically, clonal species with woody rhizomes tend to produce more bark, protect themselves better and grow taller than species with xylopodia and root crowns,” he said. 

These differences suggest that the plants have evolved two distinct strategies for resprouting from underground buds: clonal growth associated with a considerable effort to protect aerial branches; and on-spot persistence, possibly linked to a stronger focus on protecting buds in organs below ground. 

“The findings show that plants in the Cerrado are capable of investing in different strategies to protect themselves against fire,” Bombo said. “The usual view is that that they invest either in above- or below-ground strategies. The ability to invest in both reflects the extent to which woody plants have adapted to fire in the Cerrado. Having both aerial and underground fire-related strategies for regeneration and persistence enables these species to survive fire events of varying intensities.”

Next steps include examining which fire regimes favor regeneration and persistence strategies that are aerial, underground or a combination of both. “This can help us understand better the differences between above- and below-ground carbon stocks in the Cerrado,” Bombo said. “Furthermore, a comparison with different savannas around the world will show whether the results of this study might also apply to other types of vegetation exposed to fire events.”

The study was also funded via two other projects (17/02934-1 and 15/06743-0). 

Threatened biome 

The Cerrado is now the most threatened of Brazil’s biomes. Deforestation in the Amazon has decreased significantly in 2023, while destruction of native vegetation in the Cerrado has risen to record levels. In the first five months of the year, it increased 35% compared with January-May 2022. The increase corresponded to 3,532 square kilometers of destruction. These numbers, which come from the National Space Research Institute (INPE), are highly alarming because the Cerrado is the world’s most biodiverse savanna, contains 33% of Brazil’s biodiversity, and is the birthplace of the three largest river basins in South America.

As the destruction advances, important scientific research has been conducted to predict and prevent fire propagation (read more at: agencia.fapesp.br/44694) or use fire as a land management and conservation strategy (read more at: agencia.fapesp.br/26064). Other studies have also highlighted the extraordinary resilience and regenerative power of Cerrado plant species, which have evolved over millions of years in the presence of fire (read more at: agencia.fapesp.br/41100).  

About São Paulo Research Foundation (FAPESP)

The São Paulo Research Foundation (FAPESP) is a public institution with the mission of supporting scientific research in all fields of knowledge by awarding scholarships, fellowships and grants to investigators linked with higher education and research institutions in the State of São Paulo, Brazil. FAPESP is aware that the very best research can only be done by working with the best researchers internationally. Therefore, it has established partnerships with funding agencies, higher education, private companies, and research organizations in other countries known for the quality of their research and has been encouraging scientists funded by its grants to further develop their international collaboration. You can learn more about FAPESP at www.fapesp.br/en and visit FAPESP news agency at www.agencia.fapesp.br/en to keep updated with the latest scientific breakthroughs FAPESP helps achieve through its many programs, awards and research centers. You may also subscribe to FAPESP news agency at http://agencia.fapesp.br/subscribe.

 

Who is the ultimate winner of the two strategies to protect cathode for constructing long-cycle performance all-solid-state batteries?


Peer-Reviewed Publication

BEIJING INSTITUTE OF TECHNOLOGY PRESS CO., LTD

Constructing Br-Doped Li10SnP2S12-Based All-Solid-State Batteries with Superior Performances 

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CONSTRUCTING BR-DOPED LI10SNP2S12-BASED ALL-SOLID-STATE BATTERIES WITH SUPERIOR PERFORMANCES

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CREDIT: [CHUANG YU, HUAZHONG UNIVERSITY OF SCIENCE AND TECHNOLOGY]




They published their work on Oct. 18 in Energy Material Advances.

 

"Constructing a good interface between cathode and electrolyte is crucial for the development of all-solid-state battery," said Chuang Yu, a professor at the State Key Laboratory of Advanced Electromagnetic Technology at Huazhong University of Science and Technology. "Currently, strategies such as coating protect layer on cathode surface and isolating cathode/sulfide electrolyte by halide electrolyte layer are typical solutions to solve the problems at the interface between the cathode and the sulfide electrolytes, but it is not yet clear who is more suitable for sulfide-based all-solid-state batteries."

 

Yu explained that sulfide electrolytes currently used will undergo oxidative decomposition during the operation, which deteriorates to cyclability, and strategies should be employed to suppress such decomposition.

 

"Halide electrolytes have wide electrochemical windows which can compensate for the shortage of sulfide electrolytes," Yu said. "The coating layer of the cathode surface can relieve the decomposition of sulfide electrolytes. Both strategies are favored to cycle performance."

 

But it's too simplistic to think that introducing halide electrolytes can significantly improve the cycling performance of batteries. According to Yu, the use of halides introduces a new interface that is the halide/sulfide interface. The compatibility is not fully understood yet between two electrolytes and efforts should be made to explore the answer.

 

"We take Li9.9SnP2S11.9Br0.1 sulfide electrolyte as an example, employing cathode surface coating and halide/sulfide bilayer electrolyte strategies to improve the electrochemical performance of batteries," Yu said. "The cycle performance of batteries with a coating layer is excellent. The initial discharge capacity of halide/sulfide bilayer electrolyte batteries is very high but the cyclability is undesirable."

 

"This provides us with an opportunity to explore the stability of halide/sulfide interface, as batteries with bilayer electrolyte have poor cycle performance. In fact, they are indeed unstable, and after a period of contact, the impedance of the two is significantly lower than when they contact at the beginning," Yu said.

 

"The products between halide and sulfide, such as In2S3, are the main culprit causing poor cycling performance," Yu added. "Strategies should be explored to enhance the interface stability between halide and sulfide. Otherwise, the only way to significantly enhance the cycling performance of batteries is to use the coating method on the cathode surface."

 

Other contributions include Qiyue Luo, Liang Ming, Chaochao Wei, Zhongkai Wu, Ziling Jiang, Chen Liu and Shijie Cheng, State Key Laboratory of Advanced Electromagnetic Technology, School of Electrical and Electronic Engineering, Huazhong University of Science and Technology; Shiyu Liu, Wuhan National High Magnetic Field Center, Huazhong University of Science and Technology; Dong Zhang and Kecheng Cao, School of Physical Science and Technology & Shanghai Key Laboratory of High-resolution Electron Microscopy, Shanghai Tech University; Long Zhang, College of Physics and Energy, Fujian Normal University.

 

The National Key Research and Development Program (2021YFB2500200). This work is also supported by the National Natural Science Foundation of China (Nos. 52177214) and the National Key Research and Development Program (2021YFB2400300). This work uses resources of Analytical and Testing Center of Huazhong University of Science and Technology.

 

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Reference


Authors: QIYUE LUO, LIANG MING, DONG ZHANG, CHAOCHAO WEI, ZHONGKAI WU, ZILING JIANG, CHEN LIU , SHIYU LIU, KECHENG CAO , LONG ZHANG, CHUANG YU , AND SHIJIE CHENG


Title of original paper: Constructing Br-Doped Li10SnP2S12-Based All-Solid-State Batteries with Superior Performances

 

Journal: Energy Material Advances


DOI: 10.34133/energymatadv.0065


Affiliations: 1State Key Laboratory of Advanced Electromagnetic Technology, School of Electrical and Electronic Engineering, Huazhong University of Science and Technology, Wuhan 430074, P. R. China.  2School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, P. R. China. 3School of Physical Science and Technology & Shanghai Key Laboratory of High-resolution Electron Microscopy, Shanghai Tech University, Shanghai 201210, P. R. China. 4Wuhan National High Magnetic Field Center,  Huazhong  University  of  Science  and  Technology,  Wuhan  430074,  P.  R.  China.  5College  of  Physics  and Energy, Fujian Normal University, Fuzhou 350117, P. R. China

About the Author: Chuang Yu is currently a professor at Huazhong University of Science and Technology | Hust School of Electrical and Electronic Engineering. His research interest focuses on all-solid-state lithium and sodium ion electrolytes and their applications in solid-state Li and Na cells.