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Thursday, June 04, 2026

 

KRICT improves efficiency and durability of nickel-based SOECs for electrochemical CO₂ conversion



KRICT resolves high-temperature electrolyte delamination in SOECs using a scalable composite interlayer and simple dip-coating process, enabling highly efficient and durable CO₂-to-CO electrolysis




National Research Council of Science & Technology

KRICT Research Team 

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(from left) Dr. Ji Hoon Park, Dr. Jin Hee Lee, KRICT-UST student researcher Rustam Yuldashev, Dr. Min-Chul Kim, Researcher Jong-Min Kwak and Won-Bin Nam

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Credit: Korea Research Institute of Chemical Technology(KRICT)





A Korean research team has resolved a major durability issue in solid oxide electrolysis cells (SOECs), a technology that converts carbon dioxide (CO₂) into high-value chemical feedstocks.

Researchers at the Korea Research Institute of Chemical Technology (KRICT, President Seok-Min Shin), led by Drs. Min-Chul Kim, Ji Hoon Park, and Jin Hee Lee, developed a new electrolyte interface engineering technology for nickel-based SOECs. By redesigning the internal electrolyte interface structure, the team successfully prevented electrolyte layer cracking during high-temperature operation and achieved highly efficient conversion of CO₂ into carbon monoxide (CO).

SOECs are electrochemical devices that convert CO₂ into CO using electricity. The resulting CO serves as a key feedstock for syngas (CO + H₂), which can be utilized to produce sustainable aviation fuel (SAF), methanol, plastics, and industrial chemical materials.

A critical component of SOECs is the oxygen-ion-conducting electrolyte positioned between the electrodes. High-performance SOECs commonly employ two electrolyte materials together: yttria-stabilized zirconia (YSZ) and gadolinium-doped ceria (GDC). YSZ offers excellent durability but relatively low oxygen-ion conductivity, whereas GDC provides superior ionic conductivity but lower structural stability, enabling improved CO₂ conversion performance when combined.

However, the two materials exhibit different thermal expansion and shrinkage behaviors at high temperatures, causing interfacial delamination between the electrolyte layers during operation. This issue significantly degrades long-term durability and electrochemical performance. Although expensive deposition techniques such as physical vapor deposition (PVD) and pulsed laser deposition (PLD) have been explored to address this challenge, they remain costly and difficult to scale for large-area commercialization.

Instead of relying on high-cost equipment, the KRICT team employed a simple dip-coating process to form a composite intermediate layer composed of mixed YSZ and GDC powders, effectively suppressing interfacial delamination.

In simple terms, the researchers inserted a “buffer cushion layer” between the two different electrolyte materials. This composite intermediate layer absorbs thermal deformation differences, maintaining structural stability even under high-temperature conditions. During the process, the composite layer forms a new solid-solution structure that simultaneously enhances oxygen-ion transport and interfacial adhesion.

One of the key SOEC performance indicators is Faradaic efficiency, which represents how efficiently the supplied electricity is utilized to convert CO₂ into CO. Conventional SOECs typically exhibit Faradaic efficiencies of approximately 80–90%. The newly developed SOEC maintained 91% of its initial performance after 80 hours of continuous operation under a harsh 1.6 V condition, demonstrating exceptional durability along with world-class Faradaic efficiency.

The technology also significantly improved current density, a metric indicating how rapidly CO₂ can be processed per unit area. The current density increased from 0.59 to 2.14 A/cm², representing approximately a 3.6-fold improvement and achieving one of the highest performances reported for nickel-based SOECs.

In this study, the research team verified scalable fabrication conditions using coin-sized small cells and is currently expanding the technology to smartphone-sized flat-tubular cells. Because the process enables large-area manufacturing without expensive equipment, it is expected to facilitate future scale-up of electricity-driven industrial CO₂ utilization systems. However, further research on large-scale stack fabrication and renewable energy integration will still be required for commercialization.

KRICT President Seok-Min Shin stated, “This achievement simultaneously addresses the durability issue that has hindered both the commercialization and CO₂ conversion efficiency of solid oxide electrolysis cells.”

 

The study was published as the back cover article in the March 2026 issue of Advanced Science (Impact Factor: 14.1). KRICT-UST student researcher Rustam Yuldashev participated as the first author, while Drs. Min-Chul Kim, Ji Hoon Park, and Jin Hee Lee served as corresponding authors.

  

Schematic illustration of improved interfacial delamination and enhanced CO₂ electrolysis performance achieved by a composite electrolyte layer.

Customized Electrolyte Slurry Solution for Securing Interfacial Stability in Ni-Based SOECs 

Customized electrolyte slurry solution product for securing interfacial stability in Ni-based SOECs, a coin-sized small cell, and a flat-tubular cell currently under development for scale-up.

Credit

Korea Research Institute of Chemical Technology(KRICT)

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KRICT is a non-profit research institute funded by the Korean government. Since its foundation in 1976, KRICT has played a leading role in advancing national chemical technologies in the fields of chemistry, material science, environmental science, and chemical engineering. Now, KRICT is moving forward to become a globally leading research institute tackling the most challenging issues in the field of Chemistry and Engineering and will continue to fulfill its role in developing chemical technologies that benefit the entire world and contribute to maintaining a healthy planet. More detailed information on KRICT can be found at https://www.krict.re.kr/eng/

The research was supported KRICT’s institutional research program and the Korea Environment Industry & Technology Institute (KEITI) project for Intelligent Optimum Reduction and Management of Industrial Fine Dust (RS-2023-00219435).

Tuesday, May 12, 2026

 

Turning Camellia shell waste into a dual nutrient trap for wastewater cleanup



Maximum Academic Press





The study showed that the engineered material, named BC5-500, achieved strong adsorption performance, especially for phosphate, and maintained useful activity even after repeated reuse cycles and in real swine wastewater.

Nitrogen and phosphorus pollution remains a major environmental challenge because large inputs from fertilizers, domestic discharge, and industrial and agricultural wastewater can destabilize aquatic ecosystems and trigger eutrophication. Adsorption has become a widely studied treatment route because it is simple, fast, and efficient, while biochar is especially attractive due to its porous structure, surface functional groups, and tunable chemistry. Previous studies have improved nutrient capture by modifying biochar with metals such as magnesium, iron, and aluminum, but adsorption performance still varies widely with feedstock and modification method. In this context, calcium-based modification is especially promising because calcium is abundant, relatively safe, inexpensive, and has strong affinity for ammonium and phosphate. At the same time, the rapidly expanding Camellia oleifera industry generates large volumes of shell waste that are difficult to dispose of, creating a practical need to convert this residue into higher-value materials.

study (DOI:10.48130/bchax-0026-0002) published in Biochar X on 30 January 2026 by Anping Wang’s & Jie Wang’s team, Guizhou Normal University & Qiandongnan Agriculture Science Institute, reports that Ca(OH)2-modified shell biochar can effectively remove ammonium and phosphate through different but complementary chemical pathways.

To create the adsorbent, the team first cleaned, dried, ground, and pyrolyzed Camellia oleifera shells at 500 °C to obtain the base biochar BC-500, then mixed it with calcium hydroxide, washed and dried the product, and subjected it to a second pyrolysis step to produce BC5-500. They screened nine modified biochars and found BC5-500 to be the best performer, reaching adsorption capacities of 26.66 mg·g−1 for ammonium and 186.18 mg·g−1 for phosphate in preliminary tests. The material was then characterized by SEM, BET surface area analysis, FT-IR, XRD, and XPS. These analyses showed that calcium modification roughened the biochar surface, increased pore volume and average pore diameter, introduced calcium-containing active phases, and created more reactive sites for nutrient capture. Adsorption tests further showed that ammonium uptake was favored under alkaline conditions, peaking at pH 11.0, while phosphate uptake was strongest in acidic conditions, peaking at pH 2.0. Kinetic modeling showed that both adsorption processes followed the pseudo-second-order model, indicating chemisorption-dominated behavior. Isotherm analysis suggested that ammonium adsorption involved both monolayer and multilayer behavior, whereas phosphate adsorption was better described by the Freundlich model, consistent with multilayer adsorption on a heterogeneous surface. Temperature experiments showed that phosphate adsorption declined as temperature increased, while ammonium adsorption first decreased and then rose at higher temperatures. Mechanistic evidence from FT-IR, XRD, and XPS indicated that ammonium removal was driven mainly by ion exchange, whereas phosphate removal relied on both ion exchange and, more importantly, calcium-phosphate precipitation, including formation of hydroxyapatite-like products. Reuse tests showed that the biochar still retained substantial adsorption after five cycles. In actual swine wastewater, ammonium removal was limited, likely because of low concentration and competition from coexisting contaminants, but phosphate removal remained highly effective, reaching 97.73%, demonstrating particular promise for phosphorus-rich waste streams.

Overall, the study presents a practical example of waste-to-resource engineering: an abundant agricultural by-product was converted into a functional adsorbent capable of targeting two problematic nutrients in polluted water. Although its phosphate removal was much stronger than its ammonium performance in complex real wastewater, the material combined affordability, reusability, mechanistic clarity, and applicability to livestock effluents. The work therefore offers a useful foundation for developing biochar-based nutrient management technologies that link agricultural residue utilization with cleaner water and more sustainable resource recovery.

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References

DOI

10.48130/bchax-0026-0002

Original Source URL

https://doi.org/10.48130/bchax-0026-0002

Funding information

This work is supported by the project of the Guizhou Provincial Department of Science and Technology (Grant Nos Qiankehe Zhicheng [2023] 078, Qiankehe Jichu-ZK [2024] zhongdian 055, and Qiankehe Pingtai-KXJZ [2025] 023), and Projects of Forestry Research in Guizhou Province (Grant No. GUI[2022] TSLY07).

About Biochar X

Biochar X is an open access, online-only journal aims to transcend traditional disciplinary boundaries by providing a multidisciplinary platform for the exchange of cutting-edge research in both fundamental and applied aspects of biochar. The journal is dedicated to supporting the global biochar research community by offering an innovative, efficient, and professional outlet for sharing new findings and perspectives. Its core focus lies in the discovery of novel insights and the development of emerging applications in the rapidly growing field of biochar science.

Tuesday, April 28, 2026

 

Turning plastic waste into clean fuel using sunlight




Adelaide University
Turning plastic waste into clean fuel using sunlight 

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Plastics – rich in carbon and hydrogen – can be converted into a clean energy source, using sunlight.

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Credit: Adelaide University





Scientists are advancing a promising solution to two of the world’s biggest challenges – plastic pollution and clean energy – by transforming waste plastics into valuable fuels using sunlight.

new paper led by Adelaide University PhD candidate Xiao Lu explores how solar-powered technologies can convert discarded plastics into hydrogen, syngas and other useful industrial chemicals, offering a pathway toward a more sustainable, circular economy.

Globally, more than 460 million tonnes of plastic are produced each year, with millions of tonnes leaking into the environment. At the same time, the urgent need to reduce reliance on fossil fuels has driven the search for cleaner energy sources.

The research, published today in Chem Catalysis, highlights how plastics – rich in carbon and hydrogen – can be repurposed as an untapped resource rather than waste.

“Plastic is often seen as a major environmental problem, but it also represents a significant opportunity,” said Ms Lu. “If we can efficiently convert waste plastics into clean fuels using sunlight, we can address pollution and energy challenges at the same time.”

The process, known as solar-driven photoreforming, uses light-activated materials called photocatalysts to break down plastics at relatively low temperatures. These reactions can produce hydrogen – a clean fuel with zero emissions at the point of use – as well as other valuable chemicals used in industry.

Unlike traditional water splitting for hydrogen production, plastic-based photoreforming is more energy-efficient because plastics are easier to oxidise, and the process is potentially more viable for large-scale application.

Recent studies have demonstrated impressive results, according to senior author Professor Xiaoguang Duan from the School of Chemical Engineering at Adelaide University.

Researchers have achieved high rates of hydrogen production, acetic acid and even diesel-range hydrocarbons. In some cases, conversion systems have operated continuously for more than 100 hours, highlighting their growing stability and performance.

However, this study also outlines significant challenges that must be overcome before the technology can be widely deployed.

“One major hurdle is the complexity of plastic waste itself,” Prof Duan said. “Different types of plastics behave differently during conversion, and additives such as dyes and stabilisers can interfere with the process. Efficient sorting and pre-treatment are therefore essential to maximise performance and product quality.”

Another challenge lies in the design of photocatalysts. These materials must be both highly selective and durable, able to withstand harsh chemical conditions while maintaining efficiency over time. Current systems can suffer from degradation, limiting their long-term use.

“There is still a gap between laboratory success and real-world application,” Prof Duan said. “We need more robust catalysts and better system designs to ensure the technology is both efficient and economically viable at scale.”

Product separation also remains a key issue. The conversion process often produces a mixture of gases and liquids, requiring energy-intensive purification steps that can reduce overall sustainability benefits.

To address these challenges, the researchers call for a more integrated approach, combining advances in catalyst design, reactor engineering and system optimisation. Emerging concepts include continuous-flow reactors, multi-energy systems that combine solar with thermal or electrical inputs, and smarter process monitoring to improve efficiency.

Looking ahead, the team outlines a roadmap for scaling up the technology, with targets including improved energy efficiency and continuous industrial operation over the coming decades.

“This is an exciting and rapidly evolving field,” Ms Lu said. “With continued innovation, we believe solar-powered plastic-to-fuel technologies could play a key role in building a sustainable, low-carbon future.”

‘Opportunities and challenges in sustainable fuel productions from plastics’ is published in Chem Catalysis. DOI: 10.1016/j.checat.2026.101746