Wednesday, January 24, 2024

 

Fast-charging lithium battery seeks to eliminate ‘range anxiety’


Peer-Reviewed Publication

CORNELL UNIVERSITY





ITHACA, N.Y. – Cornell University engineers have created a new lithium battery that can charge in under five minutes – faster than any such battery on the market – while maintaining stable performance over extended cycles of charging and discharging.

The breakthrough could alleviate “range anxiety” among drivers who worry electric vehicles cannot travel long distances without a time-consuming recharge.

“Range anxiety is a greater barrier to electrification in transportation than any of the other barriers, like cost and capability of batteries, and we have identified a pathway to eliminate it using rational electrode designs,” said Lynden Archer, professor of engineering and dean of Cornell’s College of Engineering, who oversaw the project. “If you can charge an EV battery in five minutes, I mean, gosh, you don’t need to have a battery that’s big enough for a 300-mile range. You can settle for less, which could reduce the cost of EVs, enabling wider adoption.”

The team’s paper, “Fast-Charge, Long-Duration Storage in Lithium Batteries,” published in Joule. The lead author is Shuo Jin, a doctoral student in chemical and biomolecular engineering.

Lithium-ion batteries are among the most popular means of powering electric vehicles and smartphones. The batteries are lightweight, reliable and relatively energy-efficient. However, they take hours to charge, and lack the capacity to handle large surges of current.

The researchers pinpointed indium as an exceptionally promising material for fast-charging batteries. Indium is a soft metal, mostly used to make indium tin oxide coatings for touch-screen displays and solar panels.

The new study shows indium has two crucial characteristics as a battery anode: an extremely low migration energy barrier, which sets the rate at which ions diffuse in the solid state; and a modest exchange current density, which is related to the rate at which ions are reduced in the anode. The combination of those qualities – rapid diffusion and slow surface reaction kinetics – is essential for fast charging and long-duration storage.

“The key innovation is we’ve discovered a design principle that allows metal ions at a battery anode to freely move around, find the right configuration and only then participate in the charge storage reaction,” Archer said. “The end result is that in every charging cycle, the electrode is in a stable morphological state. It is precisely what gives our new fast-charging batteries the ability to repeatedly charge and discharge over thousands of cycles.”

That technology, paired with wireless induction charging on roadways, would shrink the size – and the cost – of batteries, making electric transportation a more viable option for drivers.

However, that doesn’t mean indium anodes are perfect, or even practical.

“While this result is exciting, in that it teaches us how to get to fast-charge batteries, indium is heavy,” Archer said. “Therein lies an opportunity for computational chemistry modeling, perhaps using generative AI tools, to learn what other lightweight materials chemistries might achieve the same intrinsically low Damköhler numbers. For example, are there metal alloys out there that we’ve never studied, which have the desired characteristics? That is where my satisfaction comes from, that there’s a general principle at work that allows anyone to design a better battery anode that achieves faster charge rates than the state-of-the art technology.”

The research was supported by the U.S. Department of Energy Basic Energy Sciences Program through the Center for Mesoscale Transport Properties, an Energy Frontiers Research Center. The researchers made use of the Cornell Center for Materials Research, which is supported by the National Science Foundation’s Materials Research Science and Engineering Center program.

For additional information, see this Cornell Chronicle story.

Cornell University has dedicated television and audio studios available for media interviews.

-30-

 

Chemists use the blockchain to simulate over 4 billion chemical reactions essential to the origins of life


CELL PRESS



Cryptocurrency is usually “mined” through the blockchain by asking a computer to perform a complicated mathematical problem in exchange for tokens of cryptocurrency. But in research appearing in the journal Chem on January 24, a team of chemists have repurposed this process, asking computers to instead generate the largest network ever created of chemical reactions which may have given rise to prebiotic molecules on early Earth.

This work indicates that at least some primitive forms of metabolism might have emerged without the involvement of enzymes, and it shows the potential to use blockchain to solve problems outside the financial sector that would otherwise require the use of expensive, hard to access supercomputers.

“At this point we can say we exhaustively looked for every possible combination of chemical reactivity that scientists believe to had been operative on primitive Earth,” says senior author Bartosz A. Grzybowski (http://grzybowski-group.net/default.asp) of the Korea Institute for Basic Science and the Polish Academy of Sciences.

To generate this network, the researchers chose a set of starting molecules likely present on early Earth, including water, methane, and ammonia, and set rules about which reactions could occur between different types of molecules. They then translated this information into a language understandable by computers and used the blockchain to calculate which reactions would occur over multiple expansions of a giant reaction network.

“The computer takes the primordial molecules and the accepted prebiotic chemistries. We coded it into the machine, and then we released it onto the world,” says Grzybowski.

Grzybowski’s team worked with chemists and computer-specialists at Allchemy, a company that uses AI for chemical synthesis planning, to generate the network using Golem, a platform that orchestrates portions of the calculations over hundreds of computers across the world, which receive cryptocurrency in exchange for computing time.

The resulting network, termed NOEL for the Network of Early Life, started off with over 11 billion reactions, which the team narrowed down to 4.9 billion plausible reactions. NOEL contains parts of well-known metabolic pathways like glycolysis, close mimics of the Krebs cycle, which organisms use to generate energy, and syntheses of 128 simple biotic molecules like sugars and amino acids.

Curiously, of the 4.9 billion reactions generated, only hundreds of reaction cycles could be called “self-replicating,” which means that the molecules produce additional copies of themselves. Self-replication has been postulated to be central to the emergence of life, but the vast majority of its known manifestations require complex macromolecules like enzymes.   

“Our results mean that with only small molecules present, self-amplification is a rare event. I don’t think that this type of self-replication was operative on primitive earth, before larger molecular structures were somehow formed,” says Grzybowski. “We see emergence of primitive metabolism, but we don’t see self-replication, so maybe self-replication appeared later in evolution.”

“If you asked me two years ago, I’d be thinking we’d need years for this type of work,” says Grzybowski. “But for a fraction of the cost, in two or three months, we finished a task of 10 billion reactions, 100k times bigger than we did previously.”

This work not only advances what we know about early prebiotic chemistry, but it also demonstrates how science can be made more accessible to researchers at smaller universities and institutions.

“Our system of education is based on elite universities mostly in the western world. It’s very hard for the developing world to even compete with these universities because they don’t have access to supercomputers,” says Grzybowski. “But if you can distribute computing in this way for a fraction of the cost, you can give other people opportunities to play.”

While the network generated in this work was performed on hundreds of computers around the world, Grzybowski suggests that this method can be used at institutions without having to pay out cryptocurrency tokens to the computers performing the calculations.

“With a platform like Golem you can connect your institution’s network and harness the entire idle power of its computers to perform calculations,” says Grzybowski. “You could create this computing infrastructure without any capital expenditure.”

Grzybowski hopes that repurposing the blockchain in this way can revolutionize the way we perform large scale calculations across the world and change how we see the value of cryptocurrency.

“I hope people in computer science can figure out how can we tokenize cryptocurrencies in some way that can benefit global science,” says Grzybowski. “Maybe society could be happier about using cryptocurrencies, if you could tell people that in the process we could discover new laws of biology or some new cancer drug,” says Grzybowski.

###

Development of all codes and algorithms described in this work described was supported by internal funds of Allchemy, Inc. and Golem Factory, GmbH. Analysis of pathways and writing of the paper by Bartosz Grzybowski was supported by the Institute for Basic Science, Korea. Grzybowski has no financial stake in Golem although he is a stakeholder of Allchemy. Additional information about declarations of interest can be found in the paper.

Chem, Roszak et al. “Emergence of metabolic-like cycles in blockchain-orchestrated reaction networks” https://cell.com/chem/fulltext/S2451-9294(23)00611-3

Chem (@Chem_CP) is the first physical science journal published by Cell Press. A sister journal to Cell, Chem, which is published monthly, provides a home for seminal and insightful research and showcases how fundamental studies in chemistry and its sub-disciplines may help in finding potential solutions to the global challenges of tomorrow. Visit https://www.cell.com/chem. To receive Cell Press media alerts, contact press@cell.com

 

Syphilis-like diseases were already widespread in America before the arrival of Columbus


Peer-Reviewed Publication

UNIVERSITY OF BASEL

Skeleton at the site in Jubuicabeira II, Brazil. 

IMAGE: 

SKELETON AT THE SITE IN JUBUICABEIRA II, BRAZIL.

view more 

CREDIT: PHOTO: DR. JOSE FILIPPINI





Researchers at the Universities of Basel and Zurich have discovered the genetic material of the pathogen Treponema pallidum in the bones of people who died in Brazil 2,000 years ago. This is the oldest verified discovery of this pathogen thus far, and it proves that humans were suffering from diseases akin to syphilis – known as treponematoses – long before Columbus’s discovery of America. The new findings, published in the scientific journal Nature, call into question previous theories concerning the spread of syphilis by the Spanish conquistadors.

The history of the emergence and spread of infectious diseases was of great importance for global health even before the Covid-19 pandemic. With modern laboratory methods, researchers can now detect the tiniest traces of DNA from pathogens in prehistoric finds. That means they can trace back how these pathogens spread historically and their evolutionary development.

An international research group led by Professor Verena Schünemann from the University of Basel, formerly at the University of Zurich, in collaboration with ETH Zurich and the Universities of Vienna and Sao Paulo, examined prehistoric bones belonging to four individuals who died 2,000 years ago in the coastal region of Santa Caterina in Brazil. For some of the individuals visible pathological changes to the prehistoric bones were detected which could indicate that the deceased were suffering from an illness similar to syphilis.

Prehistoric DNA from bones dating over 2,000 years old

The researchers used dentists’ drilling tools to remove minuscule samples of bone under sterile conditions. From those samples they isolated prehistoric genetic material (ancient DNA) belonging to the syphilis pathogen. Their study, published in the renowned scientific journal Nature, demonstrates that all the bacterial genomes that have been investigated can be attributed to the Treponema pallidum endemicum strain – that is, the pathogen that leads to bejel.

Treponematoses are a group of infectious diseases that includes the sexually transmitted disease syphilis. While syphilis as a venereal disease presents a global health risk, bejel, which is spread by skin contact, only occurs today in very arid regions of Africa and Asia.

“Our study has been able to show that endemic syphilis was already present in humid zones of Brazil around 2,000 years ago,” says Schünemann. This means that people were already becoming infected with endemic syphilis, probably via skin contact, more than 1,000 years before the arrival of Columbus in the New World.

Syphilis-like diseases originated pre-Columbus

Intense debates are still ongoing today among specialists and medical historians concerning whether Christopher Columbus’s sailors and soldiers brought sexually transmitted syphilis from the New World to the Old upon their return in 1492. The illness spread rapidly from the end of the 15th century onwards, particularly in harbor towns.

“The fact that the findings represent an endemic type of treponemal diseases, and not sexually transmitted syphilis, leaves the origin of the sexually transmitted syphilis still unsettled,” says Kerttu Majander, postdoctoral researcher at the University of Basel and one of the lead authors of the study. However, the authors consider that there is a lot to suggest that treponematoses were already widespread in Europe before Columbus’s time.

“As we have not found any sexually transmitted syphilis in South America, the theory that Columbus brought syphilis to Europe seems to appear more improbable,” agrees Schünemann. In point of fact, earlier discoveries by her group, for example in Finland and Poland, suggest that some forms of treponematoses already existed in Europe too.

Recombination could have driven the development of syphilis-like diseases

Many species of bacteria exchange traits that are of evolutionary benefit via what is known as horizontal gene transfer, or recombination. A comparison between the prehistoric DNA in the bones from Brazil and today’s pathogens shows that such recombination events have indeed taken place. “We cannot pinpoint exactly when this exchange took place, but it is probably one of the driving mechanisms in the divergence between the subspecies that cause different treponemal infections,” says Marta Pla-Díaz of the University of Basel, the other lead author of the study.

The DNA comparison also allows the date of the Treponema pallidum family’s emergence to be deduced. Their investigations show that these pathogens have arisen at some point between 12,000 and 550 BCE. The history of these pathogens therefore stretches much further back than previously assumed.

“Although the origin of syphilis still leaves room for imagination, at least we now know beyond a doubt that treponematoses were no strangers to the American inhabitants who lived and died centuries before the continent was explored by Europeans,” concludes Schünemann. She and her team are confident that advances in the analysis of prehistoric DNA could also lead to the discovery of the origin of venereal syphilis.

 

Groundwater levels are sinking ever faster around the world



Peer-Reviewed Publication

ETH ZURICH

Groundwater-​fed irrigation by an electricity-​operated pump 

IMAGE: 

GROUNDWATER-​FED IRRIGATION BY AN ELECTRICITY-​OPERATED PUMP IN SOUTHWESTERN BANGLADESH.

view more 

CREDIT: PHOTOGRAPH: AHMED ZIAUR RAHMAN





At the beginning of November, The New York Times ran the headline, “America is using up its groundwater like there’s no tomorrow.” The journalists from the renowned media outlet had published an investigation into the state of groundwater reserves in the United States. They came to the conclusion that the United States is pumping out too much groundwater.

But the US isn’t an isolated case. “The rest of the world is also squandering groundwater like there’s no tomorrow,” says Hansjörg Seybold, Senior Scientist in the Department of Environmental Systems Science at ETH Zurich. He is coauthor of a study that has just been published in the journal Nature.

Scientific evidence of rapidly depleting water resources

Together with researchers from the University of California, Santa Barbara (UCSB), he has corroborated the journalists’ worrying findings. It is not only in North America that far too much groundwater is being pumped out, but also in other parts of the world where humans have settled.

In an unprecedented feat of painstaking effort, the researchers have compiled and analysed data from over 170,000 groundwater monitoring wells and 1,700 groundwater systems over the past 40 years.

This measurement data shows that in recent decades, humans have massively expanded groundwater extraction worldwide. The water level in most groundwater-​bearing rock layers, known as aquifers, has fallen drastically almost everywhere in the world since 1980. And since 2000, this decline in groundwater reserves has accelerated. The effects are most pronounced in aquifers in the world’s arid regions, including California and the High Plains in the US, along with Spain, Iran, and Australia.

“We weren’t surprised that groundwater levels have fallen sharply worldwide, but we were shocked at how the pace has picked up in the past two decades,” Seybold says.

One of the reasons Seybold cites for the accelerated drop in groundwater levels in arid regions is that people use these areas intensively for agriculture and are pumping (too) much of the groundwater to the surface to irrigate crops, for example in California’s Central Valley.

Food cultivation and climate change exacerbate the problem

Moreover, the world’s population is growing, which means more food needs to be produced, for example in the arid regions of Iran. This is one of the countries where groundwater reserves have fallen the most.

But climate change is also exacerbating the groundwater crisis: some areas have become drier and hotter in recent decades, meaning agricultural crops need to be irrigated more heavily. Where climate change is driving a decline in precipitation, groundwater resources recover more slowly, if at all.

Heavy rainfall, which is occurring more frequently in some places as a result of climate change, is also not of any help. If the water comes in huge quantities, the soil often cannot absorb it. Instead, the water drains off at the surface without seeping into the groundwater. This problem is particularly acute in places with a high level of soil sealing, such as large cities.

Trend can be reversed

“The study also reveals good news,” says co-​author Debra Perrone. “Aquifers in some areas have recovered in places where there have been policy changes or where alternative sources of water are available for direct use or for recharging the aquifer.”

One of the positive examples is the Genevese aquifer, which supplies drinking water to around 700,000 people in the canton of Geneva and the neighbouring French department of Haute-​Savoie. Between 1960 and 1970, its level fell drastically because both Switzerland and France were pumping out water in an uncoordinated manner. Some wells even dried up and had to be closed.

To preserve the shared water resource, politicians and authorities in both countries agreed to replenish the aquifer artificially with water from the Arve River. The intention was first to stabilise the groundwater level and later to raise it – and the intervention was a success. “While the water level in this aquifer may not have returned to its original level, the example shows that groundwater levels don’t always have to go only one way: down,” Seybold says.

Other countries are reacting, too

The authorities have also had to take action in other countries: In Spain, a large pipeline has been built to carry water from the Pyrenees to central Spain, where it feeds the Los Arenales aquifer. In Arizona, water is diverted from the Colorado River into other bodies of water to replenish the groundwater reservoirs – although this does cause the delta of the Colorado River to dry up at times.

“Such examples are a ray of hope,” says UCSB researcher and lead author Scott Jasechko. Nevertheless, he and his colleagues are urgently calling for more measures to combat the depletion of groundwater supplies. “Once heavily depleted, aquifers in semi-​deserts and deserts may require hundreds of years to recover because there’s simply not enough rainfall to swiftly replenish these aquifers,” Jasechko says.

There is an additional danger on the coasts: if the groundwater level falls below a certain level, seawater can invade the aquifer. This salinises the wells, leaving the water that is pumped up unusable neither for drinking water nor for irrigating fields; trees whose roots reach into the flow of groundwater die. On the east coast of the US, there are already extensive ghost forests with not a single living tree.

“That’s why we can’t put the problem on the back burner,” Seybold says. “The world must take urgent action.”

The world has a problem: On all inhabited continents, groundwater resources whose levels have fallen to various degrees are marked by light to dark red zones.

CREDIT

(Illustrations: Scott Jasechko, UCSB)

 

Uncovering the secrets behind the silent flight of owls


Researchers investigate the aeroacoustic mechanisms that allow owls to fly silently using numerical simulations

Peer-Reviewed Publication

CHIBA UNIVERSITY

Heat map representing pressure fluctuation distributions on the owl wing surface 

IMAGE: 

THE MICRO-FRINGES ON OWL WINGS EFFECTIVELY SUPPRESS THE NOISE WHILE MAINTAINING THE AERODYNAMIC PERFORMANCE OF THE WINGS COMPARABLE TO THAT OF A WING WITHOUT THE FRINGES.

view more 

CREDIT: HAO LIU FROM CHIBA UNIVERSITY





Owls are fascinating creatures that can fly silently through some of the quietest places. Their wings make no noise while flying, enabling them to accurately locate their prey using their exceptional hearing ability while remaining undetected. This unique ability depends on many factors and has long been a hot research subject.

Studies have found associations between the ability to fly silently and the presence of micro-fringes in owl wings. These trailing-edge (TE) fringes play a crucial role in suppressing the noise produced by wing flap-induced air movement. 

Studying these fringes can lead to the development of promising methods to reduce noise caused by fluid machinery. While many studies have evaluated these fringes using flat plates and airfoils, their exact mechanisms and effects on the interactions of feathers and the different wing features in real owl wings remained unknown.

To unravel the secrets of silent owl wings, Professor Hao Liu with his colleagues, including Dr. Jaixin Rong from the Graduate School of Engineering and Dr. Yajun Jiang and Dr. Masashi Murakami from the Graduate School of Science at Chiba University in Japan, investigated how TE fringes influence both the sound and aerodynamic performance of owl wings. 

When asked about the motivation behind their study, Prof. Liu says, “Despite many efforts by many researchers, exactly how owls achieve silent flight is still an open question. Understanding the precise role of TE fringes in their silent flight will enable us to apply them in developing practical low-noise fluid machinery.” Their findings were published in the journal Bioinspiration & Biomimetics on November 17, 2023.

To understand how owl wings work, the team constructed two three-dimensional models of a real owl wing—one with and the other without TE fringes—with all its geometric characteristics. They used these models to conduct fluid flow simulations that combined the methods of large eddy simulations and the Ffowcs-Williams-Hawkings analogy. The simulations were conducted at the speed of the gliding flight of approach of a real owl.
 
Simulations revealed that the TE fringes reduced the noise levels of owl wings, particularly at high angles of attack, and maintained aerodynamic performance comparable to owl wings without fringes. The team identified two complementary mechanisms through which the TE fringes influence airflow. First, the fringes reduce the fluctuations in airflow by breaking up the trailing edge vortices. Second, they reduce the flow interactions between feathers at the wingtips, thereby suppressing the shedding of wingtip vortices. Synergistically, these mechanisms enhance the effects of TE fringes, improving both aerodynamic force production and noise reduction.
 
Emphasizing the significance of these results, Prof. Liu says, “Our findings demonstrate the effect of complex interactions between the TE fringes and the various wing features, highlighting the validity of using these fringes for reducing noise in practical applications such as drones, wind turbines, propellers and even flying cars.”
 
Overall, this study deepens our understanding of the role of TE fringes in the silent flight of owls and can inspire biomimetic designs that could lead to the development of low-noise fluid machinery.

About Professor Hao Liu
Dr. Hao Liu is a Professor at the Graduate School of Engineering at Chiba University, Japan. Prof. Liu leads the Center for Aerial Intelligent Vehicles at Chiba University. He obtained his Ph.D. from Yokohama National University in 1992. Prof. Liu has over 600 publications and 11,200 citations to his name (Google Scholar). He is one of the world’s top 2% scientists, according to Stanford University (2023). His research interests include biomechanics, biomimetics, and bio-inspired engineering.