Highly thermal conductive and electromagnetic shielding polymer nanocomposites from waste masks
Shanghai Jiao Tong University Journal Center
image:
- Fabricating low-cost, high-performance, scalable polypropylene (PP)@graphene (G) nanocomposites from recycled PP fibers in waste masks by a simple electrostatic self-assembly hot-pressing method.
- The resultant PP@G presents a high thermal conductivity of 87 W m-1 K-1 and a high electromagnetic interference shielding effectiveness of 88 dB (1100 dB cm-1).
Credit: Xilin Zhang, Wenlong Luo, Yanqiu Chen, Qinghua Guo, Jing Luo, Paulomi Burey, Yangyang Gao, Yonglai Lu, Qiang Gao, Jingchao Li, Jianzhang Li, Pingan Song.
A groundbreaking review in Nano-Micro Letters by Zhang, Gao, Song and co-workers from Beijing Forestry University, Nanjing Forestry University and University of Southern Queensland presents a closed-loop upcycling strategy that transforms COVID-era polypropylene (PP) mask waste into high-performance PP@G nanocomposites—delivering record thermal conductivity and electromagnetic shielding while cutting environmental impact and cost.
Why This Research Matters
• Overcoming Global Waste Crisis: > 950 billion masks (3.8 Mt) have been discarded since 2020; incineration releases dioxins, landfilling persists for centuries. The work converts this hazardous stream into strategic thermal-management and EMI-shielding feedstock.
• Enabling Next-Gen Electronics: High-power, high-density chips and 5G/6G modules demand lightweight, low-cost materials that simultaneously dissipate > 50 W m-1 K-1 of heat and block > 30 dB of EMI. PP@G surpasses both thresholds by 75 %, paving the way for greener data centers, EV powertrains and flexible wearables.
Innovative Design & Mechanisms
• Core-Sheath Nanostructure: Tannic-acid-decorated PP fibers (20 µm diameter) act as negatively charged “cores”; cationic PAE@GNP platelets (6 µm lateral size) electrostatically self-assemble into a continuous graphene “sheath” after 140 °C / 50 MPa hot-pressing, yielding meter-scale (1 m × 1 m) sheets.
• Aligned 3-D Phonon/Electron Highways: Face-to-face oriented GNPs create sub-100 K W-1 contact resistance—two orders of magnitude lower than random dispersions—enabling 87 W m-1 K-1 in-plane thermal conductivity and 893 S m-1 electrical conductivity at 66 wt % loading.
• Green & Scalable Process: Operates under atmospheric pressure, uses only water and food-grade tannic acid, and is fully compatible with roll-to-roll production—turning waste logistics into manufacturing assets.
Applications & Future Outlook
• Real-World Thermal Management: PP@G66 film cools 12 V LEDs by 60 °C versus commercial PI substrates; flexible PP@G heat-sinks outperform steel blocks in 1200-cycle on-off tests without delamination.
• EMI Shielding Champion: 88 dB total shielding effectiveness (1100 dB cm-1) at 800 µm thickness—> 2× higher specific SE than MXene, CNT or rGO composites—validated by Tesla-coil LED extinction and X-band radar tests.
• Circularity & Profit: Life-cycle assessment shows 3.47 MJ fossil-fuel saving and 2.53 kg CO2-eq reduction per kg vs landfill; techno-economic analysis projects $468 profit per ton of repurposed masks.
• Next-Gen Roadmap: Strategy is being extended to other fibrous plastic waste (PPE gowns, packaging films) and co-designed with 5G base-station, EV battery and aerospace thermal-EMI modules for 2026 pilot production.
Conclusions
By merging waste valorization with materials engineering, this work delivers a dual-function nanocomposite that turns pandemic pollution into a strategic resource—setting a new benchmark for sustainable thermal and EMI solutions in high-performance electronics while accelerating the transition to a circular economy.
Journal
Nano-Micro Letters
Method of Research
Experimental study
Article Title
Highly Thermal Conductive and Electromagnetic Shielding Polymer Nanocomposites from Waste Masks
No comments:
Post a Comment