Wednesday, August 02, 2023

 

The cost of climate change: 2°C global warming target is not economically reasonable unless we make major changes 



Peer-Reviewed Publication

IOP PUBLISHING

Climate change cost 

IMAGE: THE COST OF CLIMATE CHANGE: ARE THE GLOBAL WARMING TARGETS SET OUT IN THE PARIS AGREEMENT ECONOMICALLY FEASIBLE? view more 

CREDIT: IOP PUBLISHING




Climate change goals set out in the Paris Agreement are only economically reasonable if non-market factors such as human health and loss of biodiversity are prioritised, according to a new study published by Dr Taikan Oki, former Senior Vice-Rector of United Nations University headquartered in Japan, in IOP Publishing’s academic journal Environmental Research Letters.  

A multi-disciplinary, collaborative effort from researchers at 23 institutions including The University of Tokyo, National Institute for Environmental Studies, and Kyoto University, the new study provides a cost-benefit analysis of climate change including previously neglected non-market factors such as biodiversity loss and the impact on human health. The team calculated the cost of climate change for varying priority systems, estimating the total cost including mitigation between 2010 and 2099 to be 46-230 trillion US dollars.  

The results show that the financial benefits of reducing climate change are often similar to the cost of mitigation efforts. The research team estimate the cost of additional mitigation efforts to be 45 to 130 trillion US dollars, while the financial benefits of these reduction efforts range from 23 to 145 trillion US dollars. They found that for the 2°C temperature goal to be economically feasible there must be a greater emphasis placed on the future impact of biodiversity and health factors, arguing that these factors will become ever more pressing in the future. 

The study shows that climate change would be best approached in an integrated manner with biodiversity and health issues considered side-by-side with economic factors. This is especially true when non-market values are taken into full account including health factors such as diarrhoeal diseases and malaria, and the decrease of species on Earth such as fish and insects.  

Dr Oki, who was formerly the Coordinating Lead Author for the Intergovernmental Panel on Climate Change, says: “The world’s pursuit of climate goals is currently not on track. Our future will depend on how much importance we place on risks such as large-scale irreversible events, as well as how we accept and deal with them. One reason for this is that the costs of mitigation are often similar to, or in excess of, the economic benefits of reducing climate change. We must place a higher priority on non-monetary commodities such as human health and biodiversity and accelerate technological innovations to reduce the mitigation cost.” 

Dune patterns reveal environmental change on Earth and other planets


Peer-Reviewed Publication

STANFORD UNIVERSITY




Dunes, the mounds of sand formed by the wind that vary from ripples on the beach to towering behemoths in the desert, are incarnations of surface processes, climate change, and the surrounding atmosphere. For decades, scientists have puzzled over why they form different patterns.

Now, Stanford researchers have found a way to interpret the meaning of these patterns. Their results, published in Geology Aug. 1, can be used as a new tool for understanding environmental changes on any planetary body that harbors dunes, including Venus, Earth, Mars, Titan, Io, and Pluto.

“When you look at other planets, all you have is pictures taken from hundreds to thousands of kilometers away from the surface. You can see dunes – but that’s it. You don’t have access to the surface,” said senior study author Mathieu Lapôtre, an assistant professor of Earth and planetary sciences in the Stanford Doerr School of Sustainability. “These findings offer a really exciting new tool to decipher the environmental history of these other planets where we have no data.”

The scientists analyzed satellite images of 46 dune fields on Earth and Mars and studied how the dunes interact, or exchange sand. Physically, dune interactions manifest themselves as locations where the crestlines of two dunes get very close to each other. Through such interactions, dunes evolve toward a pattern that is free of defects, reflecting a state of equilibrium with local conditions. Thus, the researchers hypothesized that a high number of interactions, in turn, must signal recent or local changes in those boundary conditions. To test their hypothesis, they used data from Earth and Mars to verify how known changes in environmental conditions, such as wind direction or the amount of sand available, affected dune interactions in the dune fields. 

Finding a pattern

In a part of China’s Tengger Desert, researchers once flattened a dune field to have a baseline for understanding its subsequent reformation. The study authors analyzed satellite images of the dune field from 2016 to 2022 to see how it grew from a flat bed to large dunes in equilibrium with their environment.

“When the dunes and their patterns were not in equilibrium with their current conditions, the interaction density was high, and through time we could see it decreased consistently, as is expected from our hypothesis,” Lapôtre said. 

Next, they investigated dunes migrating through a valley in the Namib Desert to see how changes in the wind conditions, triggered by topography, impacted dune patterns. They found that dunes outside the valley displayed few defects in their patterns, but as they migrated through the valley – which starts very wide, then narrows, then becomes wide again – dunes interacted more with each other.

“As both sand and winds get funneled into the valley, the dunes feel a change in their boundary conditions, and their pattern needs to adjust,” said lead study author Colin Marvin, a PhD student in Earth and planetary sciences. “They move into the portion outside the valley and they again readjust to their unconfined conditions, and we see a drop in the number of interactions. This trend is exactly what we expected to see.”

They also found that pattern to be true on Mars, where a big dune field occurs around the north pole. There, the migrating dunes have settled into their current conditions – they’re well spaced, they look the same, they’re the same size – and because of that, they interact very little with one another. But further downwind, the winds become more variable and frost locally makes it harder for grains to be blown away. There, the dunes react to that change until they have migrated far enough into these new conditions for their pattern to have once again matured, decreasing the number of dune interactions.

Testing the tool

“We have an upper bound on the time that it takes for a given dune to adjust to changes in environmental conditions, and that is the time it takes for a dune to migrate by a distance of one dune length,” Marvin said. “We can use this to diagnose recent changes in environmental conditions on planetary bodies where we don’t have any information other than images taken from orbit or radar for example.” 

Understanding the recent climate of Mars by analyzing current dune patterns could possibly help scientists better pinpoint, for example, the latitudes and depth where future astronauts might be able to find water ice in the subsurface, Lapôtre added. The study also informs experts about the mechanics of dunes on Earth, which can help them better interpret Earth’s rock record, and thus, our planet’s distant past. On Saturn’s moon Titan, this approach could reveal information about topography around the equator and tropics, which is near where the Dragonfly Mission is going to land in the mid 2030s. 

“Topography can tell you about a lot of different things; for example, the geological history of the planet: Does Titan have tectonics? How does the interior of Titan work, and how is it coupled with the surface? Is there significant erosion?” Lapôtre said. “Interpretations of dune patterns could trigger kind of a chain reaction, where you provide a new constraint, and it’s going to be useful to a bunch of people to make a bunch of discoveries down the line.”

Because other planets have various sizes, gravities, temperatures, and compositions, their geological processes will differ. Compared with a rover that lands on one point of a planet to collect information, the satellite data of entire dune fields can greatly increase scientists’ understanding of these extraterrestrial bodies and how they can inform our understanding of Earth.

“If we want to understand what happened in the past, or if we want to predict what will happen in the future, it’s hard to do when all you have to create those models is one data point, or just one planet,” Lapôtre said. “Ultimately, this kind of information allows us to make much better interpretations of Earth’s past and also predictions of Earth’s future.”

Study co-authors are from Monash University, the University of California, Los Angeles, and the Southwest Research Institute. The research was supported by a National Center for Airborne Laser Mapping seed grant and partly supported by NASA.

 

UTokyo researchers imagine future see-through objects


Business Announcement

INSTITUTE OF INDUSTRIAL SCIENCE, THE UNIVERSITY OF TOKYO

UTokyo Researchers Imagine Future See-Through Objects 

IMAGE: PROJECT RESEARCHER NAOTO TAKAYAMA, YU UCHIKURA, AND PROFESSOR MILES PENNINGTON OF DLX DESIGN LAB AT INSTITUTE OF INDUSTRIAL SCIENCE, THE UNIVERSITY OF TOKYO (HEREINAFTER DLX DESIGN LAB ), IN COLLABORATION WITH PROFESSOR TETSU TATSUMA, ASSISTANT PROFESSOR TAKUYA ISHIDA AND PROJECT RESEARCH ASSOCIATE SEUNG HYUK LEE OF INSTITUTE OF INDUSTRIAL SCIENCE, THE UNIVERSITY OF TOKYO (HEREINAFTER IIS), HAVE PRODUCED A FIVE-MINUTE VIDEO SUMMARISING THE TECHNOLOGY FOR CREATING NANOPARTICLES USING AN INNOVATIVE APPROACH WITH LIGHT AND THE FUTURE POSSIBILITIES IT OFFERS. THE VIDEO INTRODUCES IN AN EASY-TO-UNDERSTAND MANNER HOW THESE TINY PARTICLES MAY IN THE FUTURE LEAD TO NEW MATERIALS CALLED 'METAMATERIALS' THAT CAN FREELY MANIPULATE LIGHT AND PERFORM UNIQUE PROPERTIES, SUCH AS MAKING MATERIALS APPEAR TRANSPARENT. THE VIDEO WAS PRODUCED AS PART OF DLX DESIGN LAB TREASURE HUNTING PROJECT, WHICH AIMS TO COMMUNICATE THE VALUE AND FUTURE POTENTIAL OF SCIENTIFIC RESEARCH TO THE GENERAL PUBLIC. view more 

CREDIT: INSTITUTE OF INDUSTRIAL SCIENCE, THE UNIVERSITY OF TOKYO




Researchers from the Institute of Industrial Science(IIS), The University of Tokyo, conducts a wide range of research, including physics, chemistry and biology. In this context, DLX Design Lab carries out activities aimed at fusing science, technology, and design. One of these activities is the Treasure Hunting Project, which aims to inform the general public about the value and potential of scientific research. As part of this project, in 2022-2023, DLX Design Lab produced a video introducing future 'metamaterials' in cooperation with Tatsuma laboratory (hereinafter Tatsuma Lab) at IIS.

At the beginning of the video, we introduce the 'Future Window', which would allow people to see outside from their basements. We also show the special nanoscale particles that are necessary to achieve this conceptual product.

Next, we introduce technology for easily creating these special particles with light, through work being done in the Tatsuma Lab. In summary, the particles are grown spontaneously by light using a chemical method.

A model is used to illustrate how, if special nanoparticles are created and well aligned, they could make it possible to bend light at will.

The DLX Design Lab and Tatsuma Lab collaborated to design a roadmap for the realisation of the 'Future Window'. The first step is to create particles, which must then be arranged in planes and even three-dimensionally. 

It is predicted that development of the 'Future Window' will also derive light absorbent solar panels without reflection and translucent walls and columns that allow only certain colours of light to penetrate. One day, there may be a ‘Future Window’ that transmits full colour and even heat. The ‘Future Window’ will have the same effect as looking directly at what is outside the window, rather than seeing an image as on an LCD or other display. Sunlight shines through and shadows are created. You can look in, and even bask in the sun.

While the technology behind this concept is promising, the ‘Future Window’ is still in the realm of science fiction. As this video shows, by drawing a concrete image of the future (even if it is still science fiction) researchers become keenly aware of what they need to do to get closer to that future.

DLX Design Lab's Treasure Hunting Project has so far given form to the various research results produced at IIS, and through exhibitions and workshops has communicated the excitement and potential of science to the general public. However, it is not always easy to give form to research that deals with objects not seen by the human eye such as nanomaterials and molecules, or research that is far from being applied or realised. Using moving images to visualise the future and express it in a multifaceted and easy-to-understand manner is considered very effective in communicating to the general public about the significance of research that is difficult to give form to immediately.

DLX Design Lab will continue to use various forms and means, including these videos, to contribute to communicating the "treasures" of humanity - the results of scientific research - to society.

 

What is DLX Design Lab?:

DLX Design Lab is an international design team established in 2016 within the Institute of Industrial Science at The University of Tokyo. Our mission is to “Create Value Through Design”. The goal of DLX Design Lab is to develop innovative prototypes of products and services through close collaboration between designers, researchers, engineers, or other diverse disciplines. DLX Design Lab also focuses on disseminating knowledge and nurturing future talent by organizing classes, forums, exhibitions, and workshops to share design-led innovation methods with academia, industry, government agencies and the general public.

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Video information:

https://vimeo.com/845226045

 

Interactive networks for capturing gas with high selectivity


Soft metal-organic polymer networks can adsorb selected molecules from gas mixtures by opening pores when the molecules bind.


Peer-Reviewed Publication

KYOTO UNIVERSITY

IMAGE 

IMAGE: RESEARCHERS DEVELOPED A NEW FLEXIBLE POROUS MATERIAL THAT OPENS GATES AND ADSORBS ONLY CARBON DIOXIDE AMONG VARIOUS SIMILAR GAS MOLECULES. view more 

CREDIT: MINDY TAKAMIYA/KYOTO UNIVERSITY ICEMS




“Our work demonstrates exceptional molecule recognition and separation performance by deliberately organizing the pore geometry, structural flexibility, and molecular-level binding sites within a porous coordination polymer (PCP),” says chemist Susumu Kitagawa, leader of the research team at Kyoto University’s Institute for Integrated Cell-Material Sciences.

PCPs, also known as metal-organic frameworks (MOFs), have metal ions or clusters held together by organic (carbon-based) linker groups. Choosing different metallic components and adjusting the size and structure of the organic groups can create a huge variety of crystalline materials containing pores with finely controlled sizes, structures and chemical binding capabilities. The new work goes beyond that, however, with pores that adapt when desired molecules bind to them.

“We designed a flexible PCP with a corrugated channel system that can interact with and adsorb CO2 molecules by selectively opening pores that acts as gates, allowing only the CO2 to pass through,” says Ken-ichi Otake, also of the Kyoto team. Capturing CO2 is particularly challenging, he explains, due to the molecule’s relatively small size and low affinity for many adsorptive materials.

The technical term for what the interaction between the CO2 and the PCP achieves is exclusion discrimination gating. This means that binding of molecules chosen as the extraction target, in this case CO2, initiates a synergistic structural change that enhances the binding and opens up the solid phase structure to let the bound molecule enter.

The team demonstrated the power of their system by using it to gather CO2 from mixtures containing many industrially significant molecules, including nitrogen, methane, carbon monoxide, oxygen, hydrogen, argon, ethane, ethene and ethyne.

The process is significantly more energy efficient than existing options, over a full cycle of selective gas capture and regeneration. This could be important for the development of more sustainable gas separation technologies that can support low-carbon industrial processes. Energy efficiency will also be vital for any large-scale climate engineering efforts to extract carbon dioxide from the atmosphere. These will not be practical options if they require the generation of large amounts of energy to power the cycle of extraction, release and storage.

“By building on this initial success, future research will hopefully achieve more versatile breakthroughs in a wide range of selective gas extraction processes, says postdoctoral researcher Yifan Gu, first author of the research report.
 

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Paper:
https://doi.org/10.1038/s41467-023-39470-w

 

About Kyoto University’s Institute for Integrated Cell-Material Sciences (iCeMS):
At iCeMS, our mission is to explore the secrets of life by creating compounds to control cells, and further down the road to create life-inspired materials.
https://www.icems.kyoto-u.ac.jp/


 

AniFaceDrawing: Delivering generative AI-powered high-quality anime portraits for beginners


Researchers use a generative artificial intelligence framework to create high-quality anime portraits from incomplete freehand sketches to remove creative barriers for general users


Reports and Proceedings

JAPAN ADVANCED INSTITUTE OF SCIENCE AND TECHNOLOGY

AniFaceDrawing system: Generating High-Quality Anime Portraits using AI 

IMAGE: IMAGE GENERATIVE AI FACES INHERENT DIFFICULTIES IN GENERATING IMAGES FROM INCOMPLETE LINE DRAWING WITH SMALL AREAS MISSING AND SOMETIMES EVEN FROM COMPLETE SKETCHES. THE PROPOSED ANIFACEDRAWING SYSTEM CAN GENERATE HIGH-QUALITY RESULTS THAT CONSISTENTLY MATCH THE INPUT SKETCH THROUGHOUT THE SKETCHING PROCESS. THE IMAGE DEPICTS (A) THE FINAL USER SKETCHES, (B) THE GUIDANCE IN DETAIL MODE (COLOR LINES REPRESENT THE SEMANTIC SEGMENTED PARTS), AND (C) THE GENERATED COLOR DRAWINGS FROM (A) AFTER THE FINAL REFERENCE IMAGE SELECTION. view more 

CREDIT: HAORAN XIE FROM JAIST.




Ishikawa, Japan -- Anime, the Japanese art of animation, comprises hand-drawn sketches in an abstract form with unique characteristics and exaggerations of real-life subjects. While generative artificial intelligence (AI) has found use in the content creation such as anime portraits, its use to augment human creativity, and guide freehand drawings proves challenging. The primary challenge lies with the generation of suitable reference images corresponding with the incomplete and abstract strokes made during the freehand drawing process. This is particularly true when the strokes created during the drawing process are incomplete and offer insufficient information for generative AI to predict the final shape of the drawing.

To tackle this problem, a research team from Japan Advanced Institute of Science and Technology (JAIST) and Waseda University in Japan, sought to develop a novel generative AI tool that offers progressive drawing assistance and helps generate anime portraits from freehand sketches. The tool is based on a sketch-to-image (S2I) deep learning framework that matches raw sketches with latent vectors of the generative model. It employs a two-stage training strategy through the pre-trained Style Generative Adversarial Network (StyleGAN)—a state-of-the-art generative model that uses adversarial networks to generate new images.

The team, led by Dr. Zhengyu Huang from JAIST, including Associate Professor Haoran Xie and Professor Kazunori Miyata, and Lecturer Tsukasa Fukusato from Waseda University proposed a novel "stroke-level disentanglement”, a strategy that associates input strokes of a freehand sketch with edge-related attributes, in the latent structural code of StyleGAN. This approach allows users to manipulate the attribute parameters, thereby having greater autonomy over the properties of generated images. Dr. Huang says, “We introduced an unsupervised training strategy for stroke-level disentanglement in StyleGAN, which enables the automatic matching of rough sketches with sparse strokes to the corresponding local parts in anime portraits, all without the need for semantic labels.”

This study will be presented at ACM SIGGRAPH 2023, the premier conference for computer graphics and interactive techniques and the only CORE ranking A* conference in the research fields worldwide.

Regarding the development of the tool, Prof. Xie adds, “We first trained an image encoder using a pre-trained StyleGAN model as a teacher encoder. In the second stage, we simulated the drawing process of generated images without additional data to train the sketch encoder for incomplete progressive sketches. This helped us generate high-quality portrait images that align with the disentangled representations of teacher encoder.”

To further highlight the effectiveness and usability of AniFaceDrawing in aiding users with anime portrait creation, the team conducted a user study. They invited 15 graduate students to draw digital freehand anime-style portraits using the AniFaceDrawing tool, with the option to switch between rough and detailed guidance modes for line art. While the former provided prompts for specific facial parts, the latter provided prompts for the full-face portrait based on the user’s drawing progress. Participants could pin the generated guidance once it matched their expectations, and further refine their input sketch. This tool also allowed participants to select a reference image to generate a color portrait of their input sketch. Next, they evaluated the tool for user satisfaction and guidance matching through a survey.

The team noted that the system consistently provided high-quality facial guidance and effectively supported the creation of anime-style portraits, by not only enhancing user sketches, but also by generating desirable corresponding colored images. Prof. Fukusato remarks, “Our system could successfully transform the user’s rough sketches into high-quality anime portraits. The user study indicated that even novices could make reasonable sketches with the help of the system and end up with high-quality color art drawings”. 

“Our generative AI framework enables users, regardless of their skill level and experience, to create professional anime portraits even from incomplete drawings. Our approach consistently produces high-quality image generation results throughout the creation process, regardless of the drawing order or how poor the initial sketches are,” summarizes Prof. Miyata.

In the long run, these findings can help democratize AI technology and assist users with creative tasks, thereby augmenting their creative capacity without technological barriers.

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Reference

Title of original paper:

AniFaceDrawing: Anime Portrait Exploration during Your Sketching

Authors:

Zhengyu Huang, Haoran Xie, Tsukasa Fukusato, Kazunori Miyata

Conference:

ACM SIGGRAPH 2023

Project:

http://www.jaist.ac.jp/~xie/AniFaceDrawing.html

Video:

https://youtu.be/GcL67h8QEOY

DOI:

https://doi.org/10.1145/3588432.3591548

                                   

About Japan Advanced Institute of Science and Technology, Japan

Founded in 1990 in Ishikawa prefecture, the Japan Advanced Institute of Science and Technology (JAIST) was the first independent national graduate school in Japan. After 30 years of steady progress, JAIST has become one of Japan’s top-ranking universities. JAIST counts with multiple satellite campuses and strives to foster capable leaders with a state-of-the-art education system where diversity is key; about 40% of its alumni are international students. The university has a unique style of graduate education based on a carefully designed coursework-oriented curriculum to ensure that its students have a solid foundation to conduct cutting-edge research. JAIST also works closely both with local and overseas communities by promoting industry–academia collaborative research.

 

About Associate Professor Haoran Xie from Japan Advanced Institute of Science and Technology, Japan

Dr. Haoran Xie is an Associate Professor at the Japan Advanced Institute of Science and Technology (JAIST), Japan. With a research career spanning over a decade, Dr. Xie has over 100 publications to his credit and holds a Ph.D. in Computer Graphics from JAIST. His research interests focus on User Interfaces for Augmented Intelligence—especially for content creation, machine learning, human augmentation, and other artificial intelligence (AI)-related applications. Prof. Xie’s work has garnered him many academic awards, including several Best Paper Awards in international conferences, and FUNAI Research Award for Young Scientists. His work has been reported by various medias include Tech Xplore, China Science Daily, Nikkan Kogyo Shimbun and ITmedia NEWS.

 

Funding information

This research was supported by the JAIST Research Fund, Kayamori Foundation of Informational Science Advancement, JSPS KAKENHI JP20K19845, and JP19K20316.

 

NUS scientists develop a new class of artificial water channels for more efficient industrial water purification


These self-assembling, precise and complex nanostructures can help to purify water more efficiently


Peer-Reviewed Publication

NATIONAL UNIVERSITY OF SINGAPORE

Scientists from the National University of Singapore have developed a new class of artificial water channels for more efficient industrial water purification. 

IMAGE: A TEAM OF SCIENTISTS FROM THE NATIONAL UNIVERSITY OF SINGAPORE COMPRISING (LEFT TO RIGHT) PROFESSOR PRAKASH KUMAR, PROFESSOR MANJUNATHA KINI, DR LI JIANWEI AND DR PANNAGA KRISHNAMURTHY, HAS DEVELOPED A NEW CLASS OF ARTIFICIAL WATER CHANNELS FOR MORE EFFICIENT INDUSTRIAL WATER PURIFICATION. view more 

CREDIT: NATIONAL UNIVERSITY OF SINGAPORE




Singapore, 02 Aug 2023 -- A team led by scientists from the National University of Singapore's (NUS) Department of Biological Sciences in collaboration with the French Centre for Scientific Research (CNRS) has successfully synthesised a special protein-mimic that can self-assemble into a pore structure. When incorporated into a lipid membrane, the pores permit selective transport of water across the membrane while rejecting salt (ions). These protein-mimics, known as ‘oligourea foldamers’, represent an entirely new class of artificial water channels (AWC) that can be used to improve the energy-efficiency of current methods of industrial water purification.

Current methods of water purification involve the use of reverse osmosis and membrane distillation technologies. Reverse osmosis, however, is a highly energy-intensive process as high pressures are needed to pass seawater or wastewater through a series of semi-permeable membranes to remove salts and other pollutants. In light of climate change and the growing demand for fresh water, there is an impetus to develop more energy-efficient, water-selective membranes for large-scale desalination purposes. This invention represents an excellent contribution to these efforts. The relatively high water permeability of the pores formed by these oligourea foldamers suggests that overall energy requirement for water purification can potentially be reduced.

Addressing the limitations of conventional membrane technologies

Research in this field has largely focused on fabricating membranes with aquaporins, which are naturally-occurring proteins containing pores that allow water molecules to pass through in a single file. They are known as ‘water channels’ and can be found in the cell membranes of all living cells including microbes, plant and animal cells. Due to the complex structure of aquaporin, synthesising sufficient quantities of this bulky protein for use in water purification membranes remains an expensive and time-consuming process.

In a paper published in the scientific journal Chem on 8 May 2023, a team of NUS scientists led by Professor Prakash Kumar described a breakthrough in the development of a simpler molecular component that can self-assemble to generate transmembrane channel-like structures with a pore. These structures mimic the functions of aquaporin, allowing only water molecules to cross the membrane while salts and other pollutants are rejected. The individual oligourea foldamers are also much smaller in size at just 10 amino acid-residues long – which makes them easier to modify, synthesise, and purify compared to aquaporin or other classes of AWC.

How it works

The foldamers are amphiphilic in nature, which means that they possess different charges which allow them to assemble into more complex structures, similar to how magnets tend to clump together in a ball when they are in close proximity with each other. The resulting complex, or quaternary, structures contain pore-like water channels which are further stabilised by strong bonds known as hydrophobic and electrostatic interactions.

The hydrophobic components are clustered on the exterior that allows insertion into lipid membranes. The interior (lumen) of the pore is more hydrophilic, which allows water molecules to move across the membrane while rejecting ions from passing through. And this is responsible for the selective water permeability across lipid membranes observed in lab tests. The scientists discovered that the oligourea foldamers were similar in function to natural porin-like structures, which makes them viable potential candidates for the fabrication of AWC membranes for water purification.

Greater stability and resistance to degradation

The foldamers developed by the NUS researchers were also demonstrated to be more robust compared to other AWCs.

Normal proteins are made up of amino acids joined together by peptide bonds. These peptide bonds are vulnerable to be cut by microbial enzymes that digest proteins, and such microbes exist in unprocessed water. In their research, NUS scientists replaced the peptide bonds with urea bonds, which makes the oligourea foldamers less susceptible to enzymatic and microbial degradation.

First-of-its-kind protein-mimics that self-assemble into pores

The development of the oligourea foldamers marks the first published attempt to create AWCs using short molecular chains that can self-assemble into precise nanostructures with high porosity and selectivity for water molecules.

Prof Kumar, who has a joint appointment with the NUS Environment Research Institute, said, “The discovery of this new class of artificial water channels is significant because the individual foldamer molecules do not contain any pores, unlike other AWCs where the pores are found within their larger molecular structure. In our novel design, the water-selective pores only emerge when the individual units self-assemble. The high-water permeability coupled with resistance to proteolytic degradation makes these foldamers excellent candidates for industrial water purification applications.”

Next steps

In the initial phase, the team of scientists applied the foldamers to a test membrane to demonstrate the water purification capabilities of the self-assembling molecules. For the next phase of research, the team plans to optimise the production of the foldamers and apply them to a larger membrane, before trialling its efficiency in an industrial water purification facility.  

 

Solar-driven conversion of waste plastics into their building blocks


Peer-Reviewed Publication

DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY SCIENCES

Figure Abstract 

IMAGE: INSPIRED BY THE WARMING EARTH’S GREENHOUSE EFFECT, WE DESIGN A CATALYST ARCHITECTURE THAT ENABLES WAVES SELECTIVELY TO PASS THROUGH. THIS GREENHOUSE MIMIC IS COMPOSED OF A CARBONIZED MOF CORE WITH A MESOPOROUS SILICA SHEATH. WHEN BATHED IN SUNLIGHT, THE BLACK CORE GENERATES HEAT, WHICH IS TRAPPED THEREIN BY THE INFRARED SHIELDING EFFECTS OF THE MESOPORES, THUS BOOSTING THE RECYCLING EFFICIENCY OF WASTE PLASTICS. view more 

CREDIT: CHINESE JOURNAL OF CATALYSIS




Photothermal catalysis, fueled by clean solar energy, offers an efficient solution for converting waste plastic into valuable chemicals. This catalytic process harnesses the power of solar energy and converts it into chemical energy. However, the development of photothermal catalysts that exhibit high conversion efficiency and catalytic activity poses significant challenges.

A recent breakthrough comes from a research team led by Prof. Jinxing Chen from Soochow University, China. They have successfully developed an integrated photothermal catalyst comprising c-ZIF-8 coated with a SiO2 layer. This innovative approach focuses on enhancing catalytic activity by minimizing thermal radiation loss and maximizing the localized heating effect of the catalyst. The results were published in Chinese Journal of Catalysis (https://doi.org/10.1016/S1872-2067(23)64435-3).

This study introduces a novel catalyst design approach that involves the synthesis of ZIF-8 nanoparticles using a template method. To create an integrated photothermal catalyst (c-ZIF-8@SiO2), a layer of SiO2 is coated onto the surface of ZIF-8, followed by a high-temperature carbonization treatment. The internal carbon material within the catalyst absorbs solar energy and generates heat, while the outer SiO2 layer selectively allows penetration of solar light, which is then absorbed by the carbon core. This design effectively reduces thermal radiation loss from the internal carbon core and enhances the local thermal effect during the photothermal catalysis process. Furthermore, the SiO2 shell provides a protective effect, resulting in the catalyst's high stability. Overall, this catalyst design strategy offers a universal method for enhancing the local thermal effect in photothermal catalysis and holds potential applications in the development of efficient photothermal catalytic systems.

By irradiating sunlight, the c-ZIF-8@25SiO2 catalyst can efficiently upcycle PET into valuable monomers. The PET glycolysis experiment under outdoor sunlight and the selective recovery of PET from mixed plastics further demonstrate the promising applications in photothermal catalytic PET glycolysis. Photothermal catalysis not only contributes to energy conservation and emission reduction, promoting green and sustainable development but also provides new ideas and methods for efficient chemical recycling of plastics.

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About the Journal

Chinese Journal of Catalysis is co-sponsored by Dalian Institute of Chemical Physics, Chinese Academy of Sciences and Chinese Chemical Society, and it is currently published by Elsevier group. This monthly journal publishes in English timely contributions of original and rigorously reviewed manuscripts covering all areas of catalysis. The journal publishes Reviews, Accounts, Communications, Articles, Highlights, Perspectives, and Viewpoints of highly scientific values that help understanding and defining of new concepts in both fundamental issues and practical applications of catalysis. Chinese Journal of Catalysis ranks at the top one journal in Applied Chemistry with a current SCI impact factor of 16.5. The Editors-in-Chief are Profs. Can Li and Tao Zhang.

At Elsevier http://www.journals.elsevier.com/chinese-journal-of-catalysis

Manuscript submission https://mc03.manuscriptcentral.com/cjcatal