Wednesday, July 30, 2025

 

A bolt is born! Atmospheric events underpinning lightning strikes explained





Penn State
Researchers understand the chain reaction that triggers lightning 

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Victor Pasko, left, professor of electrical engineering in the Penn State School of Electrical Engineering and Computer Science, and Zaid Pervez, a doctoral student in electrical engineering, revealed the powerful chain reaction that triggers lightning. 

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Credit: Caleb Craig / Penn State






UNIVERSITY PARK, Pa. — Though scientists have long understood how lightning strikes, the precise atmospheric events that trigger it within thunderclouds remained a perplexing mystery. The mystery may be solved, thanks to a team of researchers led by Victor Pasko, professor of electrical engineering in the Penn State School of Electrical Engineering and Computer Science, that has revealed the powerful chain reaction that triggers lightning.

In the study published today (July 28) in the Journal of Geophysical Research, the authors described how they determined strong electric fields in thunderclouds accelerate electrons that crash into molecules like nitrogen and oxygen, producing X-rays and initiating a deluge of additional electrons and high-energy photons — the perfect storm from which lightning bolts are born.

“Our findings provide the first precise, quantitative explanation for how lightning initiates in nature," Pasko said. "It connects the dots between X-rays, electric fields and the physics of electron avalanches."

The team used mathematical modeling to confirm and explain field observations of photoelectric phenomena in Earth’s atmosphere — when relativistic energy electrons, which are seeded by cosmic rays entering the atmosphere from outer space, multiply in thunderstorm electric fields and emit brief high-energy photon bursts. This phenomenon, known as a terrestrial gamma-ray flash, comprises the invisible, naturally occurring bursts of X-rays and accompanying radio emissions.

“By simulating conditions with our model that replicated the conditions observed in the field, we offered a complete explanation for the X-rays and radio emissions that are present within thunderclouds,” Pasko said. “We demonstrated how electrons, accelerated by strong electric fields in thunderclouds, produce X-rays as they collide with air molecules like nitrogen and oxygen, and create an avalanche of electrons that produce high-energy photons that initiate lightning.”

Zaid Pervez, a doctoral student in electrical engineering, used the model to match field observations — collected by other research groups using ground-based sensors, satellites and high-altitude spy planes — to the conditions in the simulated thunderclouds.

“We explained how photoelectric events occur, what conditions need to be in thunderclouds to initiate the cascade of electrons, and what is causing the wide variety of radio signals that we observe in clouds all prior to a lightning strike,” Pervez said. “To confirm our explanation on lightning initiation, I compared our results to previous modeling, observation studies and my own work on a type of lightning called compact intercloud discharges, which usually occur in small, localized regions in thunderclouds.”

Published by Pasko and his collaborators in 2023, the model, Photoelectric Feedback Discharge, simulates physical conditions in which a lightning bolt is likely to originate. The equations used to create the model are available in the paper for other researchers to use in their own work.  

In addition to uncovering lightning initiation, the researchers explained why terrestrial gamma-ray flashes are often produced without flashes of light and radio bursts, which are familiar signatures of lightning during stormy weather. 

“In our modeling, the high-energy X-rays produced by relativistic electron avalanches generate new seed electrons driven by the photoelectric effect in air, rapidly amplifying these avalanches,” Pasko said. “In addition to being produced in very compact volumes, this runaway chain reaction can occur with highly variable strength, often leading to detectable levels of X-rays, while accompanied by very weak optical and radio emissions. This explains why these gamma-ray flashes can emerge from source regions that appear optically dim and radio silent.”                        

In addition to Pasko and Pervez, the co-authors include Sebastien Celestin, professor of physics at the University of Orléans, France; Anne Bourdon, director of research at École Polytechnique, France; Reza Janalizadeh, ionosphere scientist at NASA Goddard Space Flight Center and former postdoctoral scholar under Pasko at Penn State; Jaroslav Jansky, assistant professor of electrical engineering and communication at Brno University of Technology, Czech Republic; and Pierre Gourbin, postdoctoral scholar of astrophysics and atmospheric physics at the Technical University of Denmark.

The U.S. National Science Foundation, the Centre National d’Etudes Spatiales (CNES), the Institut Universitaire de France and the Ministry of Defense of the Czech Republic supported this research.

At Penn State, researchers are solving real problems that impact the health, safety and quality of life of people across the commonwealth, the nation and around the world.

For decades, federal support for research has fueled innovation that makes our country safer, our industries more competitive and our economy stronger. Recent federal funding cuts threaten this progress.

Learn more about the implications of federal funding cuts to our future at Research or Regress.

GREEN H2

Using alcohol to reduce the costs of industrial water electrolysis




Industrial Chemistry & Materials
Comparison of conventional water electrolysis and hybrid water electrolysis 

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Hybrid water electrolysis offers two main advantages compared to conventional water electrolysis: decreasing the energy costs of producing hydrogen and converting alcohols to more valuable products

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Credit: Dulce M. Morales, University of Groningen, The Netherlands




Hybrid water electrolysis (HWE) is an emerging field that aims to overcome some of the limitations of conventional water electrolysis (CWE) for the production of green hydrogen. In CWE, two reactions take place at each of the electrodes (anode and cathode): one reaction produces hydrogen at the cathode (the hydrogen evolution reaction) and the other produces oxygen at the anode (the oxygen evolution reaction, OER). The concept of hybrid water electrolysis revolves around replacing the anode reaction of CWE (the OER), which is inefficient and requires a large amount of energy, with an alternative anode reaction that is more efficient. In this review, the team focuses on the electrooxidation of alcohols as an alternative anode reaction. Replacing the OER offers three advantages: (1) reducing the energy costs and increasing the efficiency for hydrogen production, (2) making use of abundant resources such as bio-based alcohols (like ethanol or glycerol), and (3) converting these resources into value-added products (for example, converting glycerol to lactic acid). 

“In our review paper, we examine the current state-of-the-art of hybrid water electrolysis in which the electrooxidation of alcohols is the anode process. In particular, we review studies in which the alcohol oxidation reactions were conducted under conditions relevant for industrial alkaline water electrolysis according to standards and targets set by the International Renewable Energy Agency (IRENA) and the European Clean Hydrogen Partnership (EHCP),” said Dulce M. Morales, an Assistant Professor at University of Groningen, The Netherlands. Three specific operating conditions are emphasized in this review: current density (which is proportional to how much hydrogen is produced), electrolyte composition and temperature. Additionally, the researchers identify and discuss important aspects in the field of HWE including selectivity (forming preferably one product instead of a mixture of products), circularity (in the case of the alcohol oxidation reactions, where do the alcohols come from and what happens with the products formed during HWE?), and reactor design (including novel approaches to enhance performance). This work is published in Industrial Chemistry & Materials on 03 July 2025.

Currently, the literature shows that there is a tradeoff between activity and selectivity in alcohol oxidation reactions in alkaline media. This means that current electrochemical systems can either achieve a fast reaction rate (or fast generation of products) or a high selectivity (forming preferably one product instead of a mixture of products), but not both simultaneously. This means that researchers either have to find a way to overcome this tradeoff, or find uses for mixtures of products generated from the oxidation of alcohols (for example, as feed in bioreactors). If these mixtures cannot be used as they are, the components could be separated, but separation processes are usually costly and energy-intensive. Future research should focus on separation processes that have low costs and/or low energy requirements. 

Furthermore, there is a scarce number of reports that test catalytic materials for alcohol oxidation reactions under the industrially relevant conditions of alkaline CWE, which makes it difficult to assess if these reactions could replace the conventional OER in the same devices. Research on the alcohol oxidation (and HWE in general) under these conditions is urgently needed to advance the field, as identified in this review. Only under rigorous testing, which includes industrial parameters, can possible knowledge gaps be identified. Such as catalyst stability issues due to the high alkalinity of the electrolyte and high temperature compared to typical lab-scale conditions, which use diluted electrolytes and ambient temperature. Future design of new alcohol oxidation catalysts should consider possible stability issues under such conditions.

HWE, particularly with the oxidation of alcohols as the anode reaction, may offer a realistic pathway to remediate the major downsides of CWE by lowering the cost of green hydrogen production and co-generating additional valuable products. However, as HWE is an emerging field, research efforts are still needed to understand reaction mechanisms, catalyst development, and process optimization under industrially relevant conditions. While such conditions are still unknown for HWE, for CWE these are well-defined. “With our review, we aim to encourage researchers to further investigate HWE employing the industrially relevant conditions of CWE to assess whether it is feasible to implement alternative anode reactions in conventional water electrolyzers,” Morales said. This review provides a summary of the current state-of-the-art in this topic, and an overview of challenges and opportunities for further advancement of the HWE field. 

The research team includes Floris van Lieshout and Dulce M. Morales from the University of Groningen (the Netherlands), and Eleazar Castañeda-Morales and Arturo Manzo-Robledo from the National Polytechnic Institute (Mexico). 


Industrial Chemistry & Materials is a peer-reviewed interdisciplinary academic journal published by Royal Society of Chemistry (RSC) with APCs currently waived. ICM publishes significant innovative research and major technological breakthroughs in all aspects of industrial chemistry and materials, especially the important innovation of the low-carbon chemical industry, energy, and functional materialsCheck out the latest ICM news on the blog.

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HKUST researchers pioneer breakthroughs in lithium-ion battery recycling to enhance critical metal recovery and reduce carbon emissions



Powering a circular battery economy with low-carbon innovation




Hong Kong University of Science and Technology

Friction-induced infiltration of aluminum into nickel–cobalt–manganese (NCM) cathode crystals 

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Friction-induced infiltration of aluminum into nickel–cobalt–manganese (NCM) cathode crystals: During mechanical disassembly of spent LIBs in the recycling process, residual aluminum foil undergoes frictional contact and embeds into the NCM active material. This atomic-scale aluminum incorporation alters the crystal structure and suppresses the dissolution of critical metals (Ni, Co, Mn) across various extraction systems, including acid-based, ammonia-based, and deep eutectic solvents.

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Credit: HKUST





Lithium-ion batteries (LIBs) are widely used in consumer electronics, electric vehicles, and renewable energy systems, making efficient recycling crucial for sustainability. A research team led by Prof. Dan TSANG, Professor of Civil and Environmental Engineering at The Hong Kong University of Science and Technology (HKUST), has revealed a previously unrecognized atomic-scale mechanism that obstructs efficient LIB recycling. This breakthrough challenges long-standing assumptions and sets the stage for cleaner, high-yield recovery of critical metals used in LIBs.

Through advanced characterization and first-principles modeling, the research team found that aluminum (Al) impurities—which come from the mechanical disassembly of LIBs during the recycling process—penetrate NCM (nickel–cobalt–manganese) cathode crystals and restructure the cathodes’ internal chemistry. This triggers the formation of ultra-stable aluminum–oxygen bonds, immobilizing valuable metals and suppressing the metals’ leachability, making extraction more difficult, especially in acidic solvent systems commonly used in hydrometallurgy (the use of water-based solutions to extract metals).

Overlooked Impurities, Underrated Impact: Aluminum as a Hidden Barrier to Recycling

For decades, the presence of aluminum in spent (i.e. used) LIBs has been considered an operational nuisance or a minor issue—now, it has proven to be a mechanistic disruptor that can significantly hinder recycling efforts. The HKUST researchers discovered that during the mechanical disassembly of LIBs, residual aluminum foil can infiltrate NCM (nickel–cobalt–manganese) cathode crystals through frictional contact, subtly but profoundly altering the cathodes’ internal chemistry.

Using advanced microscopy and density functional theory (DFT) modeling, the team found that aluminum atoms selectively replace cobalt, forming highly stable aluminum–oxygen bonds that anchor lattice oxygen and suppress the release of critical metals like nickel (Ni), cobalt (Co), and manganese (Mn) during leaching, making them harder to extract in recycling.

“We’ve shown that even tiny amounts of aluminum contamination can fundamentally shift how NCM materials behave in recycling systems,” said Prof. Tsang. “This demands a paradigm shift in how we manage impurity pathways in battery-to-battery recovery.”

The study further revealed that the types of solvent used in the recycling process affect how aluminum behaves, demonstrating solvent-dependent effects. For example, aluminum slows down metal release in formic acid, enhances it in ammonia, and leads to mixed outcomes in deep eutectic solvents—highlighting the need for precise chemistry-driven process design.

Building the Future of Circular Batteries

Together, these discoveries form a coherent roadmap to overcome two critical bottlenecks in LIB recycling: impurity interference and energy intensity. By combining precision impurity analysis with smart decomposition strategies, the research equips industry and policymakers with the tools needed to scale sustainable battery recovery systems.

“We’re not just solving problems—we’re reframing what efficient, climate-aligned battery recycling looks like,” Prof. Tsang emphasized.

These innovations also align with the United Nations Sustainable Development Goals (SDGs), particularly those focused on responsible consumption and production, affordable and clean energy, and climate action.

Global Collaboration and Scalable Impact

HKUST’s battery recycling research is actively advancing from lab-scale discovery to industrial translation. Led by Prof. Tsang, the team’s findings were recently featured as the back cover of Advanced Science (Volume 12, Issue 21, June 2025), in a paper titled “Dissolution of Spent Lithium-Ion Battery Cathode Materials: Overlooked Significance of Aluminum Impurities”.

Co-authors include Prof. Tsang’s PhD student ZHANG Yuying, former postdoctoral fellows Dr. LIU Kang (now Professor at Qingdao University of Technology) and Dr. WANG Mengmeng (now Hundred Talents Program Research Fellow of the Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences) as well as collaborators at the University of California, Berkeley.


High-performance triboelectric nanogenerator based on a rotating-switch structure for efficient wind energy harvesting





Tsinghua University Press




Harnessing wind energy, especially in environments with low wind speeds, has long been a challenge for traditional technologies like electromagnetic generators, which often struggle with efficiency and are costly to maintain. A team of materials scientists led by Professor Ding Nan from Inner Mongolia University has recently proposed a RS-TENG, offering a novel approach to address this issue. Designed to significantly improve the performance of TENGs, the RS-TENG uses mechanical triggering switches to enhance the instantaneous current pulses during rotational motion, greatly increasing power density. This innovative design addresses key issues of low current output, especially in low-wind-speed conditions, enabling power delivery to small, energy-efficient electronic devices in remote areas.

The team published their review in Energy Materials and Devices on June 24, 2025.

The RS-TENG operates at a constant rotational speed, generating an instantaneous current 3.2 times higher than that of the non-switching TENG. Additionally, its response time is reduced by 89%, thereby ensuring significantly improved efficiency. At a wind speed of 2 m/s, it generates a power density of 10.4 mW·m-2·m-1·s. The device's structure and functionality are optimized through innovative design, including wind cups and integrated materials. The unique setup results in a significant increase in both short-circuit current and transferred charge, enhancing its overall efficiency. Additionally, the RS-TENG has demonstrated the capability to power up to 413 commercial LEDs directly, further highlighting its potential in practical applications. The RS-TENG has shown significant potential for harnessing wind energy, even at low wind speeds of 4 m/s, and can efficiently power systems like digital thermometers and wireless transmitters. This research opens new avenues for enhancing power density at low wind speeds and represents a critical step towards improving the viability and sustainability of wind energy as a primary renewable resource.

Other contributors include Juan Pan, Wuliang Sun, Ying Zhan, Xiaoxia Lv, Xin Li, Yaxin Huang, Ding Nan from the College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot, China; and Baodong Chen from the Beijing Institute of Nanoenergy and Nanosystems, Chinese Academy of Sciences, Beijing, China.

This work was supported by the National Natural Science Foundation of China (Grant No. 62431006), the Inner Mongolia Major Science and Technology Project (Grant No. 2020ZD0024), Local Science and Technology Development Project of the Central Government (Grant No. 2021ZY0006, 2022ZY0011), Natural Science Foundation of Inner Mongolia (Grant No.2024LHMS05046) and Inner Mongolia Autonomous Region key Research and Technological Achievements Transformation Plan Project (Grant No. 2023YFHH0063).

 

About Energy Materials and Devices

Energy Materials and Devices is launched by Tsinghua University, published quarterly by Tsinghua University Press, exclusively available via SciOpen, aiming at being an international, single-blind peer-reviewed, open-access and interdisciplinary journal in the cutting-edge field of energy materials and devices. It focuses on the innovation research of the whole chain of basic research, technological innovation, achievement transformation and industrialization in the field of energy materials and devices, and publishes original, leading and forward-looking research results, including but not limited to the materials design, synthesis, integration, assembly and characterization of devices for energy storage and conversion etc.

 

Only 10% of early childhood teachers have enough time to get their work done



Teachers report working in the evenings, over weekends due to shortage of planning time




University of Georgia





Early childhood teachers face high rates of stress and job turnover. A new study from the University of Georgia found that a lack of planning time may only make things worse.

Planning periods are times when teachers are away from students and working on other professional tasks. For early education teachers, those tasks include things like documenting children’s development and progress, writing lesson plans and communicating with parents.

Though teachers working in elementary, middle or high schools are required to have this time, it isn’t mandated for early education teachers. That may be why the new study found that only about 1 in 10 early childhood teachers said they had enough time to complete all their work.

Most of them are doing their planning and work tasks during their personal time, which includes evenings and weekends,” said Erin Hamel, lead author of the study and an assistant professor in UGA’s Mary Frances Early College of Education. “That can be problematic because it encroaches on their personal lives and can lead to burnout and turnover.”

Early childhood teachers report getting 37 minutes less than their scheduled planning time each week

The study surveyed 106 teachers and 104 directors of early childhood education centers. The researchers asked how much planning time teachers are scheduled for and how much they actually get.

On average, the teachers report receiving 37 minutes less than what they’re scheduled for.

“The work day of an early childhood teacher is unpredictable. If the program is short staffed, teachers may have to use their planning time to help out another classroom,” said Hamel. “Or if a child gets sick a teacher may need to be with the child in a separate room until the parents come. That could take up her planning time.”

Lack of planning time often leaves teachers scrambling to get everything done on time. This leaves teachers with no choice but to work during their personal time, adding to their stress, the researchers said.

Most childhood education center directors know teachers work over the weekend

Many directors know their teachers are short on time, with about half acknowledging that teachers frequently have to work over the weekend.

So why don’t directors just give teachers more planning time?

Every state requires a specific teacher-to-child ratio in the classroom. If there aren’t enough teachers present, it can impact the safety of young children, the quality of care and leave the center open to legal trouble.

"Taking care of teachers is an important part of taking care of children.” —Erin Hamel, College of Education

“Directors are between a rock and a hard place,” said Hamel. “If a center is short staffed and the director needs three teachers in a classroom to meet ratio requirements, it may mean sacrificing teachers’ planning time because planning time is not mandatory.

“Licensing and ratio requirements are essential because they keep children safe and improve the quality of care. In the current context of teacher shortages, directors are forced to make difficult staffing decisions that may negatively impact teachers because it requires them to give up their planning or break times. Most teachers readily do this for the children, but it takes a toll.”

Only 16 states require planning time for early childhood teachers

Currently, only 16 states mandate some form of planning time for early childhood teachers. But more states are now considering doing the same.

“Teachers who are stressed tend to interact with children less sensitively, so adequate planning time can have an indirect impact on children’s educational experience,” said Hamel. “Taking care of teachers is an important part of taking care of children.”

This study was published in Early Childhood Research Quarterly and co-authored by Rachel Schachter.