Extract fertilizer from air and water
Pulsed electrolysis opens a path toward sustainable production of nitrogen compounds such as ammonia and urea / Review article by Dandan Gao
Johannes Gutenberg Universitaet Mainz
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Dr. Dandan Gao with the two main authors of the current review article, Dr. Bahareh Feizi Mohazzab and Kiarash Torabi from JGU (fltr)
view moreCredit: photo/©: Shikang Han
Nitrogen-based fertilizers are essential for modern agriculture, and compounds like ammonia and urea are also widely used in industry. However, their conventional production and use pose major environmental challenges. The industrial synthesis of ammonia through the Haber-Bosch process consumes vast amounts of energy, while excessive fertilizer runoff contaminates soil and water. Moreover, nitrous oxide, a byproduct of nitrogen compound production, is a potent greenhouse gas with nearly 300 times the global warming potential of carbon dioxide. "Pulsed electrolysis could offer a sustainable alternative," says Dr. Dandan Gao, a chemist at Johannes Gutenberg University Mainz (JGU). "This emerging method uses excess nitrogen from air and water as the starting material, enabling the energy-efficient production of valuable compounds such as ammonia and urea." In a recently published Minireview in Angewandte Chemie, Gao, colleagues from JGU, and collaborators from the Harbin Institute of Technology in Shenzhen, China, summarize the latest progress in this promising field and outline key directions for future research. "By providing a clear overview of what has been achieved so far and what remains to be explored, we aim to accelerate advances toward sustainable nitrogen conversion," Gao explains. "Ultimately, we want to help turn waste nitrogen in the environment into useful products."
Traditionally, ammonia is produced through the Haber-Bosch process, which requires high temperatures (400 to 500 degrees Celsius) and pressures, making it highly energy-intensive. In contrast, pulsed electrolysis enables ammonia and even urea formation at room temperature using electricity, ideally sourced from solar or wind power. In this process, two electrodes are immersed in nitrate- or nitrite-containing water. When an electrical voltage is applied, these nitrogen compounds are reduced to ammonia. Unlike conventional electrolysis, pulsed electrolysis varies the voltage and current, which not only enhances reaction efficiency but can also align naturally with intermittent renewable energy sources.
Comparison of results from all available studies
"Because a comprehensive overview of this topic was still missing, we analyzed all available studies on pulsed electrolysis and compared their findings," says Gao. "Our goal is to highlight the potential of this environmentally relevant technology and provide a roadmap for future work." In the long run, Gao envisions that pulsed electrolysis could help redefine the nitrogen cycle, making fertilizer production cleaner, more efficient, and better aligned with a renewable energy future.
Journal
Angewandte Chemie
Method of Research
Survey
Subject of Research
Not applicable
Article Title
Reductive Nitrogen Species Activation via Pulsed Electrolysis: Recent Advances and Future Prospects
Article Publication Date
24-Oct-2025
Floating hydrovoltaic device harvests energy from raindrops
A new water-integrated droplet electricity generator achieves high electrical output when floating on water surfaces
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The conventional droplet electricity generator (C-DEG) uses a metal bottom electrode and a rigid substrate, and is generally employed on land. In contrast, the new water-integrated floating droplet electricity generator (W-DEG) uses water as the bottom electrode and substrate to enable land-free applications and promote scalability.
view moreCredit: ©Science China Press
Raindrops are more than just a source of fresh water—they also carry untapped energy that falls freely from the sky. Scientists have long sought to capture this natural resource, but traditional droplet electricity generators face challenges such as low efficiency, heavy materials, and limited scalability. Now, a team from Nanjing University of Aeronautics and Astronautics has introduced a breakthrough: a floating droplet electricity generator that directly incorporates natural water as part of its structure, offering a lightweight, cost-effective, and environmentally friendly approach to renewable energy. Their findings are published in National Science Review.
Conventional droplet electricity generators typically rely on a rigid substrate and a metal bottom electrode to produce electricity when raindrops strike a dielectric film. While capable of generating voltages in the hundreds of volts, these designs are heavy, expensive, and limited by the use of solid construction materials. By contrast, the new water-integrated device floats directly on a body of water, with the water itself serving as both the supporting substrate and the conductive electrode. This nature-integrated design reduces material weight by about 80% and cost by about 50% compared to conventional systems, while delivering comparable electrical performance.
When raindrops fall onto the floating dielectric film, the incompressibility and high surface tension of water provide the mechanical strength needed to support the impact, allowing droplets to spread effectively. At the same time, the ions in water act as efficient charge carriers, enabling it to function as a reliable electrode. Together, these properties ensure that the floating generator produces high peak output voltages—around 250 volts per droplet—on par with conventional devices that rely on metal electrodes and rigid substrates.
Durability is another strength of the design. Tests showed that the W-DEG maintained performance across a wide range of conditions, including varying temperatures, salt concentrations, and even exposure to outdoor lake water with biofouling. Unlike many energy devices that degrade in harsh environments, the floating generator continued to operate stably thanks to the chemical inertness of its dielectric layer and the resilience of its water-based structure. To further enhance stability, the team exploited water’s high surface tension to design drainage holes that allow water to pass downward but not upward, creating a self-regulating system for removing excess droplets. This innovation ensures that the device avoids water accumulation, which could otherwise reduce output.
Scalability is promising aspect of the floating droplet electricity generator. The researchers demonstrated a 0.3-square-meter integrated device—significantly larger than previously reported droplet generators—that could power 50 light-emitting diodes (LEDs) simultaneously. The integrated system also charged capacitors to useful voltages within minutes, showing the potential to power small electronics and wireless sensors. With further development, such systems could be deployed across lakes, reservoirs, or coastal regions, where they would harvest renewable electricity without occupying valuable land resources.
“By letting water itself play both structural and electrical roles, we’ve unlocked a new strategy for droplet electricity generation that is lightweight, cost-effective, and scalable,” said Prof. Wanlin Guo, a corresponding author of the study. “This opens the door to land-free hydrovoltaic systems that can complement other renewable technologies like solar and wind.”
The implications of this work extend beyond rainwater harvesting. Because the device floats naturally on water surfaces, it could be deployed in diverse aquatic environments for powering environmental monitoring systems, such as sensors that track water quality, salinity, or pollution. In regions with frequent rainfall, it could provide a distributed energy solution that supplements local grids or powers off-grid applications. Moreover, the concept of “nature-integrated design”—using abundant natural materials like water as functional components—could inspire new approaches in green technology.
The researchers note that while the laboratory results are promising, challenges remain before large-scale deployment. Real raindrops vary in size and velocity, which could affect performance, and ensuring the integrity of large dielectric films in dynamic outdoor conditions will require further engineering. Still, the demonstration of a durable, efficient, and scalable prototype marks an important step toward practical applications.
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