It’s possible that I shall make an ass of myself. But in that case one can always get out of it with a little dialectic. I have, of course, so worded my proposition as to be right either way (K.Marx, Letter to F.Engels on the Indian Mutiny)
Thursday, December 22, 2022
WILDCAT!
French railways face 100-mn-euro bill over Christmas strike
Travellers are furious about the disruption which comes despite a 12-percent pay deal for rail workers.
France's railways face a 100-million-euro ($106-million) bill over a Christmas rail strike organised by ticket inspectors without union backing which has caused a major backlash from travellers, a minister said on Thursday.
Transport Minister Clement Beaune called the stoppage over the the coming weekend "incomprehensible and unjustifiable". "It will probably cost the company around a 100 million euros," he told Franceinfo radio. "We don't need that at the moment and we need everyone to start talking again."
Several hundred thousand travellers have seen their tickets cancelled this weekend, the first Christmas since 2019 without major Covid-19 health concerns. The SNCF has offered to reimburse double the face value of cancelled tickets if travellers are unable to book an alternative.
"I'm totally fed up. It's becoming a nightmare. You can't take people as hostages like this," pensioner Christian Petit told AFP at a station in Lyon.
Resolving the dispute -- which has led to the cancellation of two out of five long-distance trains this weekend -- is complicated by the way the strikers have organised themselves.
The stoppage has been coordinated by an informal collective of train managers on Facebook, rather than via union representatives, and the strikers have made no public statement.
The SNCF says unions have already negotiated a pay rise of 12 percent over two years for staff, which is in line with inflation and superior to most private-sector settlements. "We've done everything to try to avoid the strike," SNCF boss Jean-Pierre Farandou said on Thursday. More disruption looms over the New Year weekend when unions have informed management of another possible strike.
"What we expect from the management of the SNCF today is that they find a solution in the next few hours, and I mean in the next few hours," Economy Minister Bruno Le Maire told Sud Radio.
France Faces Wave of Transport Strikes on Christmas Week-End
Albertina Torsoli, Bloomberg
Commuters wait at Gare de Lyon in Paris during a strike organised by SNCF controllers on Dec 2. Photographer: Stephane De Sakutin/AFP/Getty Images , Photographer: STEPHANE DE SAKUTIN/AFP
(Bloomberg) -- France is bracing for another Christmas of travel disruption after the state-owned railway operator SNCF was forced to cancel one in three TGV high-speed trains because of strikes.
The measures will be put in place on Thursday evening due to a strike notice by on-board client managers, according to the SNCF’s website. Roughly the same situation is expected Dec. 24 and Dec. 25, SNCF said.
No disruption is expected for international travel on Thalys and Eurostar trains during the period, SNCF added, aside from that caused by UK strikes. There are currently no Eurostar trains scheduled for Dec. 26 due to a strike at Britain’s Network Rail, though further walkouts planned for this week were called off Wednesday after staff received an improved offer.
The walkouts are among many taking place across various industries — especially in the UK — as inflation spirals and cost of living becomes harder to afford. While protests and demands for higher salaries are legitimate, there’s no justification for strikes at such a crucial time, French government spokesman Olivier Veran said in an interview on France Inter Wednesday.
Families are desperate to reunite after two difficult Covid-19-blighted Christmases, he said. “There should be no strikes but a truce for Christmas,” Veran said. “This is not the time to take the French hostage.”
SNCF has pledged to reimburse double the price of the lost tickets. Veran said he wasn’t yet in a position to estimate what the reimbursements will cost the company.
Air France-KLM’s French carrier also faces possible strikes in the coming two weeks, although the airline has pledged to take all its clients to their destination nonetheless.
(Updates with Eurostar strike cancellation in third paragraph.)
Spain approves trans rights bill that has split the left
Hazel WARD Thu, December 22, 2022
Lawmakers on Thursday passed a transgender rights bill allowing anyone 16 and over to change gender on their ID card, putting Spain on track to becoming one of the few countries to allow the change with a simple declaration.
Approved by 188 votes with 150 against and seven abstentions, the bill now moves to the Senate where, if left unchanged as expected, it will become law in weeks.
The bill simplifies the procedure for changing gender on a person's national identity card, allowing them to request the change based on a simple statement.
It also bans conversion therapies, promotes non-discrimination against LGBTQ people in the workplace and seeks "to advance the inclusion" of transgender women in particular who tend to be disproportionately affected.
But the text has sparked a bitter dispute among activists in Spain's powerful feminist lobby and LGBTQ equality campaigners.
In Europe, Denmark was the first country to grant such a right in 2014.
The legislation is a flagship project of the equality ministry, which is held by Podemos, the radical left-wing junior partner in the Socialist-led coalition.
"That's how history is made," tweeted Equality Minister Irene Montero, thanking "the feminist majority" alongside a snapshot of the vote count and footage of LGBTQ campaigners applauding. - 'Transphobia' -
A strong advocate of gender self-identification who has denounced opposition to the law as "transphobia", Montero has said the law would "depathologise trans lives and guarantee trans people's rights".
Until now, adults in Spain have been allowed to request the change with a medical report attesting to gender dysphoria and proof of hormonal treatment for two years, while minors needed judicial authorisation.
But the bill drops that requirement and lets anyone from the age 16 freely change their designated sex on their ID card. Even those as young as 12 can apply, but only under certain conditions.
After submitting the request, the applicant must confirm the demand three months later, then it will become valid.
Adopted by the cabinet in June 2021, the bill has sparked tensions between Podemos, the driving force behind the legislation, and the Socialists in Prime Minister Pedro Sanchez's government who have tried to modify it.
It has also divided the feminist movement between those supporting Montero and the powerful feminist lobby allied with the Socialists who are opposed to the text.
One of the most vocal opponents was Sanchez's former deputy Carmen Calvo, who abstained, telling local media she could never vote with the right-wing but could not bring herself to vote in favour of the bill. - 'Neither voluntary or optional' -
"When gender is asserted over biological sex, it does not seem to me to be a step forward in a progressive direction; it seems to be a step backwards," she told El Mundo daily in September.
"The state has to provide answers for transgender people, but gender is neither voluntary nor optional."
Activists fear the law will be open to abuse and erode women's rights, allowing men who self-identify as women to compete in women's sport or request a transfer to women's prisons.
They have also raised alarm about minors having the right to self-determine gender. Under the bill, 12- and 13-year-olds need parental and judicial approval to do so, while 14- and 15-year-olds just need parental approval.
Although the Socialists pushed for an amendment that would have extended judicial authorisation up to the age of 15, it was rejected in what was widely seen as a victory for Montero and Podemos.
"The transgender law which will be approved today in parliament symbolises the Socialist party's biggest defeat by Podemos during this legislature," the conservative El Mundo newspaper said Thursday.
The centre-left El Pais said it was "one of the laws that had most strained the coalition government".
Tensions around the legislation prompted Socialist LGBTQ activist Carla Antonelli -- the first and only trans woman to serve as a lawmaker -- to resign from the party after decades of activism.
"We have seen part of the Socialist party and the feminist movement go from defending the rights of the trans minority to ruthlessly boycotting our very existence," she wrote in an op-ed published by El Pais on Thursday.
Scotland passes law easing gender change rules
Stuart GRAHAM Thu, 22 December 2022
Lawmakers in Scotland passed a contentious law Thursday making it easier and faster for people to change their gender, despite a rare rebellion within the ruling Scottish National Party (SNP) and "concerns" from the UK government.
The legislation, which garnered 86 votes in favour but 39 against in Scotland's devolved parliament in Edinburgh, drops the requirement for a gender dysphoria medical diagnosis in order for someone to alter their gender.
"The motion is therefore agreed and the Gender Recognition Reform Scotland Bill is passed," presiding officer Alison Johnstone said to loud applause from the public gallery.
People aged 16 and 17 will also now be allowed to change their gender, despite efforts by some Scottish lawmakers to keep the age at 18.
The law reduces from two years to three months -- or six months for 16-17 year-olds -- the time needed for an applicant to live in their new gender before it is officially recognised.
An additional three-month reflection period is also required, during which time those who have initiated or are considering altering their gender can change their mind.
Opponents of the law fear it could be a danger to women and girls, particularly around the provision of single-sex spaces.
But the Scottish government insists the legislation will not impact the Equality Act, which allows for trans people to be excluded from single-sex spaces such as changing rooms and shelters.
Scotland's First Minister Nicola Sturgeon, who has faced one of the biggest internal rebellions of her eight-year tenure over the issue, said the previous system to change gender was "intrusive, traumatic and dehumanising".
- JK Rowling backed protests -
"I am a feminist. I will argue for women's rights. I will do everything I can to protect women's rights for as long as I live," Sturgeon said during a lengthy debate on the law.
"But I also think it's an important part of my responsibility to make life a little bit easier for stigmatised minorities in our country, to make their lives a bit better and to remove some of the trauma they live with on a day-to-day basis."
Rachael Hamilton, a Conservative lawmaker, said society as a whole was at risk from the law.
"While most of us around Scotland are good, decent, reasonable people, rapists are not, sex offenders are not," she said.
"It is ignorant to the extreme to believe they will not take advantage of loopholes that are ripe for exploitation."
The slow passage of the bill through the Scottish parliament has been marred by repeated protests, and seen Sturgeon pitted against Harry Potter author JK Rowling as well as some members of her own party.
Rowling, who has been accused of being transphobic and subjected to threats on social media since publishing a controversial essay on gender identity in 2020, backed protests in Edinburgh over the legislation.
Meanwhile SNP lawmaker Ash Regan, who was minister for community safety, resigned in October saying her conscience would "not allow" her vote for the law.
The UK government said on Thursday it shared "the concerns that many people have regarding certain aspects of this bill" and vowed to "look closely" at it.
London could try to block it coming into force if ministers believe the new Scottish law will conflict with UK-wide legislation.
A senior German official said on Thursday Twitter should join other tech firms in being directly monitored by the European Commission, saying the company’s erratic behaviour under new owner Elon Musk posed a threat to free speech.
Sven Giegold, the state secretary in charge of competition policy at Germany’s economy ministry, pointed to Twitter’s abrupt suspension of journalists’ accounts and restrictions on the access to some links.
In a letter to two European Commissioners, Giegold called on the EU to launch an investigation and said the Commission should act to prevent what he called Twitter’s “anti-competitive behaviour”.
Twitter did not immediately respond to requests for comment. The European Commission confirmed receiving the letter and said it would reply in due course, adding that it was following the developments at Twitter closely.
“General terms and conditions that change almost every hour, erratic justifications for extensive restrictions on links and the blocking of journalists threaten freedom of competition and pose a risk to freedom of expression, information and the press,” Giegold wrote on Twitter, while sharing his letter.
Musk on Tuesday said he was stepping down as Twitter chief executive.
His $44 billion takeover in October has been marked by chaos and controversy. Changes in December to Twitter’s privacy policy and the suspension - and reinstatement - of journalists’ accounts drew condemnation from news organizations, advocacy groups and officials across Europe.
(REUTERS)
CRIMINAL CRYPTO CAPITALI$M
FTX founder Sam Bankman-Fried released on massive $250 million bond
The enormous personal recognizance bond, which federal prosecutors described as perhaps the largest ever, is to be co-signed by his parents and two other suretors, and will be secured by his parents’ Palo Alto, California, home.
As a further condition of release, Bankman-Fried must live in his parent’s home with electronic bracelet and other electronic monitoring.
He was prohibited from opening new lines of credit, businesses and barred from transactions over $1,000, except to pay lawyers.
Bankman-Fried left the courthouse in lower Manhattan Thursday afternoon.
U.S. Magistrate Judge Gabriel Gorenstein said federal law required him to accept the bond package unless he concluded there were no way to ensure Bankman-Fried would appear for trial. That was not the case, said the judge, who noted that the defndant has no history of prior arrests or violence.
"If you fail to appear in court or violate any of the conditions, a warrant will be issued for your arrest" and the bond could be forfeited, the judge warned.
Gorenstein said the release conditions, particularly the electronic monitoring, “will go very far in ensuring the defendant will be kept track of.”
“Mr. Bankman-Fried perpetrated a fraud of epic proportions” and harmed many victims, Assistant U.S. Attorney Nicolas Roos said, describing the government's case as strong and that includes multiple cooperating witnesses.
Referring to Bankman-Fried's steep fall, Roos said: “His financial assets, which were once in the billions, have diminished significantly.”
The defendant, dressed in a dark suit and tie with a light-colored shirt, accented with ankle shackles, spoke just once, to tell the judge he understood the legal proceedings.
“My client voluntarily consented to come to New York and face these charges,” defense lawyer Mark Cohen said. He called the release conditions a “strong package” that the defense accepted.
The 30-year-old one-time mogul had been held in the Bahamas following his arrest earlier this month, but was extradited to the U.S. late Wednesday to face prosecution in New York.
Two former business associates of Bankman-Fried, Caroline Ellison and Gary Wang, also have pleaded guilty to federal charges and agreed to cooperate with prosecutors investigating the alleged fraud scheme, Manhattan U.S. Attorney Damian Williams said.
Like Bankman-Fried, Ellison and Wang also have been accused of civil charges by the U.S. Securities and Exchange Commission and the Commodity Futures Trading Commission.
Before the spectacular financial collapse, Bankman-Fried was the face of FTX, a global company with more than 130 affiliates that allowed individual investors to trade cryptocurrencies, growing to be the third-largest exchange by volume. The company's commercials featured prominent celebrities, and its logo appeared on an NBA stadium and on MLB umpire uniforms.
Bankman-Fried is accused of using billions of dollars of FTX funds to make personal investments and millions of dollars in contributions to political campaigns while repaying billions in loans owed by Alameda Research, a cryptocurrency hedge fund that he also founded, according to court documents.
The California man is charged with two counts of wire fraud conspiracy, two separate counts of wire fraud, and one count of conspiracy to commit money laundering.
Each of the charges carry maximum punishments of 20 years in prison.
Bankman-Fried also is charged with conspiracy to commit commodities fraud, conspiracy to commit securities fraud, and conspiracy to defraud the United States and commit campaign finance violations, each of which carries a maximum sentence of five years.
According to the SEC court complaint, Ellison, the former chief executive of Alameda Research, furthered the alleged fraud scheme by following Bankman-Fried's instructions to manipulate the price of FTT, an FTX-issued crypto security token.
Wang, an FTX co-founder and former chief technology officer, created FTX’s software code that allowed Alameda to divert FTX customer funds, and enabled Ellison to misappropriate FTX customer funds for Alameda’s trading activity, the SEC court complaint alleged.
Climate change: evaluating CO2 emissions from land use with greater precision
Determining greenhouse gas emissions precisely and consistently is essential for mitigating climate change. Due to different methods and definitions, however, the land-use-related CO2 fluxes calculated from global models deviate from the data furnished to the UN in the country reports. In their reports, for example, the countries frequently combine natural and indirect, human-caused CO2 flows on managed land. This leads to a certain amount of double-counting of natural CO2 absorption by the ground and vegetation, causing an overestimation of the remaining carbon budget to limit global warming to 1.5°C or 2°C.
A team led by LMU geographers Clemens Schwingshackl and Julia Pongratz has now harmonized the various calculation methods at country level and determined possible reasons for outstanding differences. The researchers’ analysis allows country targets to reduce CO2 emissions from land use to be evaluated with greater precision, thereby supporting the fair distribution of climate mitigation goals.
The high mortality in the early stages of life is a common phenomenon in fish and other species, but it is little studied due to its complexity. A study by the University of Barcelona and the Centre for Advanced Studies of Blanes (CEAB-CSIC) has analysed whether this mortality in the sharpsnout seabream (Diplodus puntazzo), a species of the Mediterranean with an important commercial interest, occurs by chance or whether it is genetically determined. The results, published in the journal Scientific Reports, show that the survival of this fish in the first months has a genetic basis and it is associated with the time of birth.
The sharpsnout seabream is an animal that lives in rocky coastal reefs and seagrass meadows in the Mediterranean and the eastern Atlantic, where it plays a key ecological role, since it is the only Mediterranean fish with a wide prey spectrum, including preys such as sponges, echinoderms and coelenterates. In order to find out the causes for its mortality during the early stages of life, the researchers compared genomic data to phenotypic and environmental data from recruits, individuals that only settled in October after being larvae in the plankton, and survivors, six-month-old fish that had survived the winter.
The researchers analysed a total of 105 individuals from three populations along a geographical gradient, in particular in the coastal areas of Blanes, Jávea and Agua Amarga. “Analysing in three different populations the individuals that settle for the first time and those that survive enabled us to identify parallel evolutionary processes associated with environmental and phenotypical variables”, the researchers note.
The information on the analysed fish and the environments was inferred using the analysis of its otoliths, bones in the inner part of the ear. “These are bone structures that show daily growth rings that allow us to see when it catches an individual, a series of variables like when it was born and its size, when it settled and what growth rate it will have or how many days it was in the plankton; they also allow us to record environmental variables of the temperature and the lunar cycles”, they say.
The individuals that survive are the ones who are born later
The results showed clear signs of selective mortality mostly associated with birth time, sea surface temperature and growth rate during the larval stage. "It is very interesting to see that in this species, which reproduces in late summer and early autumn, the individuals that survive best are those that are born later, in cooler conditions, and grow more slowly, and mostly, that genetics is important in that survival", they add.
Using sequencing techniques, 122 loci were found to be significantly associated with these phenotypic and environmental variables in parallel in the three populations analysed. Finding parallel genomic changes between these populations supports the idea of a genetic basis for this mortality during the first six months of life. "Our study is the first to do a genomic approach and in different localities. It is very important to have this sampling, as it shows that the results cannot be due to chance", they stress.
“Therefore —they continue—, we treat different populations as survival replicates and look mostly at changes in the same direction.
A pioneer methodology
The methodology used in this study offers a prototype for future genomic and ecological studies of this and other species which will enable the researchers to assess the causes that determine selective mortality in a wild state during this early stage. “To date, there were no studies that combined the methodologies and types of sampling we used. Our study sets the bases to analyse the survival in early stages in nature, to determine whether this process is by chance or whether it is genetically determined and to understand with long-term studies how polymorphisms are maintained in the populations in the presence of selection”, the researchers note.
Sequencing project for the genome of the sharpsnout seabream genome
Although there is a high number of identified loci associated with these features, most of them have not been localized in the closest available genome to the sharpsnout seabream, which suggests that they are in poorly conserved regions and that it is necessary to have phylogenetically closer genomes for comparison. In this sense, one of the co-authors of the study, IRBio researcher Carlos Carreras, has led a study by the Catalan Initiative for the Earth Biogenome Project to sequence the sharpsnout seabream and it is currently under the annotation phase. “We hope that in the future, this helps us to identify where the loci are and the role they can play in this species’ survival”, they say.
Studies to analyse interannual variation
The continuation of this study will be to see how selection can change within and between localities and years, as, according to the researchers, there is an interannual variation that can be very important. "The fact that we have found selective mortality has led us to want to know more. We are not only obtaining the genome of the sharpsnout seabream with the quality of international standards, but we are also analysing other years. We want to see parallel evolutionary processes, and how they vary over time, as well as to see if there is local adaptation in each population. And, with all of this, we want to identify candidate genes in which we can find out their function", they conclude.
This study is led by Prof. Kun Yang (Department of Earth System Science, Tsinghua University). Surface solar radiation (Rs) data is the essential information for the development of solar power usage to mitigate the ongoing climate change. To meet China’s carbon neutrality goal, China has invested and planned heavily in the solar photovoltaic systems. However, future projections of Rs based on climate models contain large uncertainties due to internal climate variability, model uncertainty, and scenario uncertainty, which have not been eliminated by previous studies. Moreover, the model biases in Rs and the underlying drivers have yet to be quantified.
By integrating the high-quality observations and the latest Coupled Model Intercomparison Project Phase 6 (CMIP6) model data of Rs, the research team explored the model bias of CMIP6 models in Rs and quantified the physical causes of the model bias in China. The systematic bias in Rs in CMIP6 models is revealed to be caused by clouds and aerosols, resulting in largely uncertain projections for future changes in Rs (No.1).
To correct this effect, the team used historical biases of models to constrain the future projections of Rs under three possible future scenarios based on emergent constraints, an approach with a solid physical basis for narrowing the uncertainties of future climate projections through the combination of an ensemble of climate simulations with contemporary measurements. The constrained results substantially reduce the projection uncertainties by about 56% in the mid-21st century (No.2). Moreover, they found that the constraints using the combined effect of the TCC and Rs-clear biases can account for about 81% of the projection uncertainties using R.
Moreover, the constrained projections of Rs show a spatial pattern significantly favorable for the future solar energy layout. They found that the mean Rs change during 2050-2069 relative to 1995-2014 is brightening. Particularly in North China and Southeast China with higher power demand, the constrained projections present more significant brightening (No.3).
With increased anthropogenic forcing, the constrained future changes become weaker brightening in eastern China and more dimming in western China (No.3). “Low anthropogenic emissions under the carbon neutrality actions would not only help to mitigate global warming but also increase solar energy potential, consequently creating positive feedback for building a climate-resilient society”, Yang says.
Better estimates and uncertainties of future Rs changes improves the reliability of climate projections to facilitate effective investment of solar power in China. Their results highlight the need to consider the change in spatial pattern of future Rs when making policies or decisions associated with future solar energy deployment.
(a) The relationship between the future Rs during 2050-2069 in SSP1-2.6 (a low-emission scenario) and the historical bias in Rs during 1961-2014 for the 24 models. (b) Comparisons of raw and constrained projections of Rs in SSP1-2.6. Rs projections are constrained by the historical bias in Rs (red bars) and the historical bias in TCC and Rs-clear, respectively (blue bars). Photo credit: Yanyi He and Kun Yang.
Future changes (shading; in W•m-2) in the 20-year mean of Rs during 2050-2069 relative to the 1995-2014 mean from constrained values in three possible future scenarios, i.e., SSP1-2.6 (a), SSP2-4.5 (b) and SSP5-8.5 (c), with the 66% confidence interval shown as contour. Photo credit: Yanyi He and Kun Yang.
The Earth's deep-sea trenches are some of the least explored places on Earth - as they are very difficult to access, are pitch black and the pressure is extremely high. Collecting samples and making reliable measurements of the processes that regulate the turnover of organic material in the deep is therefore difficult.
In recent years, however, researchers from the Danish Center for Hadal Research (HADAL) at University of Southern Denmark have carried out a number of expeditions to deep-sea trenches.
They have developed and applied sophisticated underwater robots, and they have demonstrated in several published studies that the steep deep-sea trenches accumulate various material including organic carbon that ends up at the bottom of the trenches.
The bottom of a deep-sea trench can therefore be a veritable deposition hotspot for microbial life forms that converts the material.
Carbon accumulates in the trenches
In three recent studies, the researchers report that hard-to-decompose organic carbon, including so-called black carbon, accumulates in large quantities at the bottom of the trenches. The studies can be found here, here and here.
Black carbon consists of particles formed during burning of fossil fuels, wood and forests; activities that also lead to the release of CO2. The occurrence of black carbon is thus an indicator of the extent of fossil burning. The particles themselves can also contribute to warming, as they are carried by wind and weather to ice-covered areas, e.g. polar regions, where they settle on ice and snow, increasing heat absorption and thus the melting.
- And now we see that large amounts of black carbon end up at the bottom of deep-sea trenches, says Ronnie N. Glud, professor and head of the Danish Center for Hadal Research.
Samples from more than six kilometers depth
More concretely, the research team has calculated that every year, somewhere between 500,000 and 1,500,000 tonnes of black carbon is stored in the hadal deep-sea; that is the part of the seabed that lies at a depth of more than six kilometers.
In comparison, 6,600,000 – 7,200,000 tonnes of black carbon are emitted annually from the burning of fossil fuels.
The researchers base their calculations on sediment samples that they have retrieved from various deep-sea trenches, exceeding six km deep and thus part of the hadal realm. The hadal zone covers 1% of the seabed.
Not only are disproportionately large amounts of black carbon being deposited in the deep; the same happens for other resilient, hard-to-decompose carbons. In fact, the studies show that every square meter in the central parts of a deep-sea trench buries 70 times more resilient carbon compared to the deep sea in general.
- Although the hadal zone only makes up a very small part of the seabed, disproportionately more carbon is stored here than in the deep sea in general, says Ronnie N. Glud and elaborates:
- So, despite the fact that the deep trenches have a relatively high microbial turnover, the hadal zone and the deep-sea trenches are overlooked reservoirs of stored carbon and thus represent a piece of the global carbon cycle and counteract the rate at which Co2 accumulates in the atmosphere.
The researchers cannot say with certainty where the deep-sea trenches' content of deposited carbon comes from; this work is still going on.
The sea as a landfill
But the black carbon can be the result from burning fossil fuels in nearby countries such as New Zealand, Australia and Chile, which sends black carbon out to sea with the wind.
This hypothesis aligns with the fact that the black carbon content is highest in trenches that are close to industrialized countries, while trenches that are close to less industrialized countries such as Papua New Guinea have a lower content of black carbon. However, factors such as wind direction, ocean currents are forest fires may confound such relations.
According to Ronnie N. Glud the deep-sea trenches act as deposit zones for organic material. The process is facilitated by frequent earthquakes, which are characteristic of the hadal systems.
The earthquakes carry large amounts of material down into the deepest parts of the trenches and bury it in oxygen-free sediments. Here, the material will accumulate over centuries and millennia.
Thus, one may want to ask whether the deep-sea trenches are suitable for carbon storage?
- Man has always used the sea and the deep sea as a dumping ground in the pretense of being "out of sight out of mind". But today we know this is not true. The ocean, rich in life, and its biological and biogeochemical processes are important for the function of the globe – this also applies to the hadal trenches, says Ronnie N. Glud.
Other materials end up in the deep-sea trenches
The fact that man-made, resilient, hard-to-decompose organic material (partly from our burning of fossil fuels), reaches the bottom of our deepest deep-sea trenches, does not surprise Ronnie N. Glud.
- In the past, it was believed that the deep-sea trenches were deserted and devoid of life, and that they were unaffected by what happened at the surface. Hence the name "hadal", which is derived from the name of the realm of Death in Greek mythology (HADES), he says, continuing:
- Today we know that the hadal trenches have a rich and diverse life, are dynamic and very diverse, and that material from land and the surface finds its way all the way to their interior – unfortunately this also includes plastic and pollutants. For example, we have previously demonstrated that hadal sediments contain surprisingly high levels of mercury.
The abundant carbon on Earth might offer a rich, renewable resource for clean, sustainable energy. The technology — called carbon-based electrochemical catalysis — that could make green energy conversion possible exists, according to an international collaboration investigating recent advancements, but is not ready for broad application.
While the catalysts have yet to hit the sweet spot of performance and cost-effectiveness needed for industrial deployment, the researchers said, there are clear pathways to advance the technology through the promise of carbon-based metal-free electrocatalysts (C-MFECs). The team published their review on December 15 in Nano Research Energy.
“It is imperative to develop sustainable and clear energy as well as related storage devices to alleviate the energy shortage and environmental pollution,” said co-corresponding author Liming Dai, Scientia Professor, Australian Research Council Laureate and funding director of the Australian Carbon Materials Centre, School of Chemical Engineering, University of New South Wales. “In this article, we provide a concise but critical review of recent progress in the development of rationally designed C-MFECs with high-performance activity sites for energy-related reactions and systems. We also discuss current challenges and future opportunities to provide forward-looking guidance for their potential application in various catalytic processes of practical significance.”
Electrochemical catalysts typically accelerate a reaction at an electrode, which often require a metal. The metals that work best, such as platinum, are scarce and expensive. More common metals, such as iron and copper, are cheaper but less efficient in accelerating a full reaction. According to co-corresponding author Chuangang Hu, corresponding author and a professor from the State Key Laboratory of Organic-Inorganic Composites, College of Chemical Engineering, Beijing University of Chemical Technology, C-MFECs offer a potential alternative to noble metal-based and transition metal-based electrocatalysts.
“Low-cost, high-activity and stable metal-free alternatives for renewable energy technologies are desperately desired,” Hu said. “After about a decade worldwide extensive research and development and with the availabilities of these newly developed strategies, C-MFECs show potential applications in renewable energy and environmental technologies of practical significance. Mainly since 2015, many strategies have been reported to improve electrochemical catalytic activity by designing C-MFECs through intrinsic catalytic structure adjustment and rational assembly.”
In their assessment of the last seven years, roughly, of scientific literature, the researchers found that the most recent work includes how to control focus on structure design and regulation of intrinsic catalytic active sites, or how efficiently and effectively the catalyst causes the desired reaction. The recent work also includes advancements in construction of 3D assembly and composite structures and investigations into the mechanisms underlying C-MFECs
“Recent years have witnessed tremendous progress in the field of C-MFECs,” Dai said. “Rational design and regulation of the configuration and structure of C-MFECs could be used for tailoring advanced catalysts with desired properties and performance, which could make C-MFECs overtake metal-based catalysts in the race to the renewable energy technological marketplace.”
To support the advancement of C-MFECs as a metal alternative for practical applications at a large scale, Dai said there is still an “urgent” need to develop efficient and controllable synthesis strategies. According to Dai and Hu, researchers should focus on overcoming key challenges to generate large-scale, reproducible C-MFECs with uniform and stable electrocatalytic active sites for specific reactions. These barriers include developing better synthesis and precise control of C-MFECs’ structure and properties; improving the characterization of the catalysts and their active sites to better inform theoretical modeling; developing multifunctional C-MFECs; and preparing C-MFECs for industrialization.
“Our goal is to provide a timely and concise, but critical review of recent progress in the development of C-MFECs as meaningful guidance for the design and synthesis of high-performance C-MFECs.” Hu said.
Other contributors include Jixin Yan, Fenghui Ye, Xinyue Ma and Zhihai Fang, State Key Laboratory of Organic-Inorganic Composites, College of Chemical Engineering, Beijing University of Chemical Technology; and Quanbin Dai, Department of Macromolecular Science and Engineering, Case School of Engineering, Case Western Reserve University in the United States.
The National Natural Science Foundation of China and the Fundamental Research Funds for the Central Universities financially supported this work in part.
Nano Research Energy is launched by Tsinghua University Press, aiming at being an international, open-access and interdisciplinary journal. We will publish research on cutting-edge advanced nanomaterials and nanotechnology for energy. It is dedicated to exploring various aspects of energy-related research that utilizes nanomaterials and nanotechnology, including but not limited to energy generation, conversion, storage, conservation, clean energy, etc. Nano Research Energy will publish four types of manuscripts, that is, Communications, Research Articles, Reviews, and Perspectives in an open-access form.
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